Enhancement of visible-light-driven photocatalytic performance of BiOBr nanosheets by Co2+ doping

被引:35
|
作者
Huang, Wenmao [1 ]
Hua, Xin [1 ]
Zhao, Yaping [1 ,2 ]
Li, Kai [1 ]
Tang, Liping [1 ]
Zhou, Man [1 ]
Cai, Zaisheng [1 ]
机构
[1] Donghua Univ, Coll Chem Chem Engn & Biotechnol, Minist Educ, Key Lab Sci & Technol Ecotext, Shanghai 201620, Peoples R China
[2] Donghua Univ, Fundamental Expt Chem Ctr, Shanghai 201620, Peoples R China
基金
中国国家自然科学基金;
关键词
MICROSPHERES; DEGRADATION; BIOCL; NANOPARTICLES; MECHANISMS; REDUCTION; OXIDATION; GRAPHENE; CATALYST; LIQUID;
D O I
10.1007/s10854-019-01869-x
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this work, Co2+ modification influence on the visible-light-induced photocatalytic performance of BiOBr was investigated. BiOBr and Co2+-doped BiOBr (Co/BiOBr) nanosheets were fabricated through a facile solvothermal way. The morphology, structure, chemical composition and optical properties of the photocatalysts were characterized by various techniques. The results confirmed the successful synthesis of Co/BiOBr nanosheets and indicated the doped Co2+ had little influence on the surface morphology and crystal structure but expanded the light absorption region. Photoelectrochemical measurements were applied to evaluate the semiconducting properties of Co/BiOBr, and the results implied that compared with the undoped sample, Co/BiOBr had higher charge transfer efficiency and smaller charge transfer resistance which were beneficial to the improvement of visible-light-driven photocatalytic performance. The as-synthesized Co/BiOBr nanosheets exhibited excellent catalytic activity and stability in the photodecomposition of contaminants.
引用
收藏
页码:14967 / 14976
页数:10
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