Hydrothermal synthesis and characterization of the lutetium borate-nitrate Lu2B2O5(NO3)2 • 2H2O

被引：14
|
作者：
Ortner, Teresa S. [1 ]
Wurst, Klaus [1 ]
Hejny, Clivia [2 ]
Huppertz, Hubert [1 ]
机构：
[1] Leopold Franzens Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, Innrain 80-82, A-6020 Innsbruck, Austria
[2] Leopold Franzens Univ Innsbruck, Inst Mineral & Petrog, Innrain 52, A-6020 Innsbruck, Austria
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2016年 / 233卷
关键词：
Lutetium borate-nitrate; Pyroborate; Nitrate; Hydrothermal; Crystal structure; FUNDAMENTAL BUILDING-BLOCKS; BOND-VALENCE PARAMETERS; EARTH BASIC NITRATES; CRYSTAL-STRUCTURES; MAGNESIUM BORATE; HYDROGEN-BONDS; COLEMANITE; MINERALS; GEOMETRY; SPECTRA;
D O I：
10.1016/j.jssc.2015.11.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The lutetium diborate-dinitrate Lu2B2O5(NO3)(2) center dot 2H(2)O was discovered through a hydrothermal synthesis from Lu(NO3)(3) center dot H2O and H3BO3. The compound crystallizes in the space group PT (no. 2) with the lattice parameters a=789.52(5), b=988.62(6), c=1460.33(8) pm, alpha=90.83(1), beta=101.75(1), and gamma=110.02(1) (Z=4). Isolated [B2O5](4-) units show coplanar alignment and the coordinating [NO3](-) groups are stacked perpendicular to the borate plane. Thereby, a novel, open arrangement solely built up from diborate and nitrate groups at a 1:1 ratio is formed. Additionally, Lu2B2O5(NO3)(2) center dot 2H(2)O is characterized by vibrational spectroscopy (IR/Raman). (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码：329 / 334
页数：6
相关论文
共 50 条
  • [1] Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87]NO3 • 2H2O
    Ortner, Teresa S.
    Huppertz, Hubert
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2017, 72 (09): : 677 - 685
  • [2] Hydrothermal synthesis and crystal structure of [Zn(pytpy)2][NO3]2·2H2O
    Yu Ding
    Feng Wang
    Zong-Jun Ku
    Lian-Sheng Wang
    Huan-Bo Zhou
    Journal of Structural Chemistry, 2009, 50 : 1212 - 1215
  • [3] Hydrothermal synthesis and crystal structure of [Zn(pytpy)2][NO3]2•2H2O
    Yu Ding
    Feng Wang
    Ku, Zong-Jun
    Wang, Lian-Sheng
    Zhou, Huan-Bo
    JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 50 (06) : 1212 - 1215
  • [4] Synthesis and structure of La[B5O8(OH)(H2O)]NO3•2H2O
    Li, LY
    Li, GB
    Liao, FH
    Lin, JH
    ACTA PHYSICO-CHIMICA SINICA, 2005, 21 (07) : 769 - 773
  • [5] Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3
    Ortner, Teresa S.
    Wurst, Klaus
    Perfler, Lukas
    Tribus, Martina
    Huppertz, Hubert
    JOURNAL OF SOLID STATE CHEMISTRY, 2015, 221 : 66 - 72
  • [6] Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B5O8(OH)(H2O)x] NO3•2H2O [RE = Nd (x=0.85), Sm (x=0)]
    Ortner, Teresa S.
    Wurst, Klaus
    Joachim, Bastian
    Huppertz, Hubert
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (22) : 3659 - 3665
  • [7] Hydrothermal synthesis and characterization of [Ni(phen)3]2[Mo8O26]•2H2O
    Wang, RZ
    Xu, JQ
    Yang, GY
    Li, YF
    Xing, YH
    Li, DM
    Liu, SQ
    Bu, WM
    Ye, L
    Fan, YG
    SOLID STATE SCIENCES, 2000, 2 (07) : 705 - 710
  • [8] Synthesis, structure analysis and thermodynamics of [Ni(H2O)4(TO)2](NO3)2•2H2O (TO=1,2,4-triazole-5-one)
    Chen, San-Ping
    Li, Na
    Wei, Qing
    Gao, Sheng-Li
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2010, 100 (03) : 1115 - 1120
  • [9] Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)•2H2O
    Wang, Yongjiang
    Pan, Shilie
    Tian, Xuelin
    Zhou, Zhongxiang
    Liu, Gang
    Wang, Jide
    Jia, Dianzeng
    INORGANIC CHEMISTRY, 2009, 48 (16) : 7800 - 7804
  • [10] Hygroscopic La[B5O8(OH)]NO3 • 2H2O: Insight into the evolution of borate fundamental building blocks
    Zhao, Biao-Chun
    Sun, Wei
    Ren, Wei-Jian
    Huang, Ya-Xi
    Li, Zucheng
    Pan, Yuanming
    Mi, Jin-Xiao
    JOURNAL OF SOLID STATE CHEMISTRY, 2013, 206 : 91 - 98
12345