MoSi2 coating on Mo substrate for short-term oxidation protection in air

被引:86
作者
Alam, Md. Zafir [1 ]
Venkataraman, B. [1 ]
Sarma, Bijoy [1 ]
Das, Dipak K. [1 ]
机构
[1] Def Met Res Lab, Hyderabad 500058, Andhra Pradesh, India
关键词
High temperature alloys; Oxidation; Diffusion; Surfaces and interfaces; HIGH-TEMPERATURE OXIDATION; MOLYBDENUM DISILICIDE; MO-9SI-18B ALLOY; MICROSTRUCTURE; DIFFUSION; COMPOSITES; BEHAVIOR; KINETICS; GROWTH; MO5SI3;
D O I
10.1016/j.jallcom.2009.07.141
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Because of their excellent oxidation resistance and high specific strengths, bulk MoSi2 and MoSi2-based composites are used for several high temperature applications. In this work, the effectiveness of a MoSi2 coating formed by pack siliconizing method has been evaluated in providing short-term oxidation protection to pure Mo substrate at 1100 and 1500 degrees C. In terms of weight change, coated Mo showed about similar to 300 times better oxidation resistance than the bare metal at 1100 degrees C. The MoSi2 coating provided good oxidation protection to Mo up to 1 h at 1500 degrees C. The evolution of the surface morphology and the microstructure of the above coating during oxidation has been studied. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:335 / 340
页数:6
相关论文
共 24 条
[1]   Study on reaction and diffusion in the Mo-Si system by ZrO2 marker experiments [J].
Byun, JY ;
Yoon, JK ;
Kim, GH ;
Kim, JS ;
Choi, CS .
SCRIPTA MATERIALIA, 2002, 46 (07) :537-542
[2]  
Chao P. J., 1961, NIOBIUM TANTALUM TUN, P250
[3]   OXIDATION OF MOSI2-BASED COMPOSITES [J].
COOK, J ;
KHAN, A ;
LEE, E ;
MAHAPATRA, R .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1992, 155 (1-2) :183-198
[4]   PROTECTION OF MOLYBDENUM FROM OXIDATION BY MOLYBDENUM DISILICIDE BASED COATINGS [J].
COX, AR ;
BROWN, R .
JOURNAL OF THE LESS-COMMON METALS, 1964, 6 (01) :51-69
[5]  
DOYCHAK J, 1994, INTERMETALLIC COMPOU, V1, P977
[6]  
GAGE PR, 1965, T METALL SOC AIME, V233, P832
[7]  
Govindarajan S, 1995, SURF COAT TECH, V76, P7, DOI 10.1016/0257-8972(95)02524-3
[8]   Evolution kinetics and microstructure of MoSi2 and Mo5Si3 surface layers on two-phase Mo-9Si-18B alloy during pack-cementation and high-temperature oxidation [J].
Ito, K ;
Hayashi, T ;
Yokobayashi, M ;
Numakura, H .
INTERMETALLICS, 2004, 12 (04) :407-415
[9]   Oxidation behavior of Mo-9Si-18B alloy pack-cemented in a Si-base pack mixture [J].
Ito, K ;
Murakami, T ;
Adachi, K ;
Yamaguchi, M .
INTERMETALLICS, 2003, 11 (08) :763-772
[10]   ENGINEERING LIMITATIONS OF MOSI2 COATINGS [J].
KIRCHER, TA ;
COURTRIGHT, EL .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1992, 155 (1-2) :67-74