Fluorous phase chemistry: a new industrial technology

被引:128
作者
Dobbs, AP
Kimberley, MR
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ Exeter, Sch Chem, Exeter EX4 2NN, Devon, England
关键词
fluorous; fluorous biphasic catalysis; fluorous synthesis; liquid-liquid extraction; solid-liquid extraction;
D O I
10.1016/S0022-1139(02)00202-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The fluorous biphasic system has become increasingly popular amongst the academic community as a phase separation and immobilisation technique. It has revolutionised both the synthetic organic and catalytic communities. However, the fluorous biphasic system has still to be fully embraced by the industrial sector. The major developments in fluorous chemistry are reviewed, with a particular emphasis on potential industrial applications. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:3 / 17
页数:15
相关论文
共 73 条
  • [1] Barthel-Rosa LP, 1999, COORDIN CHEM REV, V190, P587
  • [2] GEOMETRICAL MODEL FOR CHEMICALLY BONDED TMS AND PDS PHASES
    BERENDSEN, GE
    GALAN, LD
    [J]. JOURNAL OF LIQUID CHROMATOGRAPHY, 1978, 1 (04): : 403 - 426
  • [3] A soluble fluorous phase polymer support
    Bergbreiter, DE
    Franchina, JG
    [J]. CHEMICAL COMMUNICATIONS, 1997, (16) : 1531 - 1532
  • [4] Copper-catalyzed aerobic oxidation of alcohols under fluorous biphasic conditions
    Betzemeier, B
    Cavazzini, M
    Quici, S
    Knochel, P
    [J]. TETRAHEDRON LETTERS, 2000, 41 (22) : 4343 - 4346
  • [5] Palladium-catalyzed cross-coupling of organozinc bromides with aryl iodides in perfluorinated solvents
    Betzemeier, B
    Knochel, P
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (23) : 2623 - 2624
  • [6] Phosphorus(III) ligands with fluorous ponytails
    Bhattacharyya, P
    Gudmunsen, D
    Hope, EG
    Kemmitt, RDW
    Paige, DR
    Stuart, AM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (24): : 3609 - 3612
  • [7] Phosphorus(III) ligands in fluorous biphase catalysis
    Bhattacharyya, P
    Croxtall, B
    Fawcett, J
    Fawcett, J
    Gudmunsen, D
    Hope, EG
    Kemmitt, RDW
    Paige, DR
    Russell, DR
    Stuart, AM
    Wood, DRW
    [J]. JOURNAL OF FLUORINE CHEMISTRY, 2000, 101 (02) : 247 - 255
  • [8] A coiled coil with a fluorous core
    Bilgiçer, B
    Fichera, A
    Kumar, K
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (19) : 4393 - 4399
  • [9] Selective sulfonylation of 1,2-diols and derivatives catalyzed by a recoverable fluorous tin oxide
    Bucher, B
    Curran, DP
    [J]. TETRAHEDRON LETTERS, 2000, 41 (49) : 9617 - 9621
  • [10] Perfluorocarbon-soluble catalysts and reagents and the application of FBS (fluorous biphase system) to organic synthesis
    Cavazzini, M
    Montanari, F
    Pozzi, G
    Quici, S
    [J]. JOURNAL OF FLUORINE CHEMISTRY, 1999, 94 (02) : 183 - 193