Carbon nanotube-ruthenium hybrid towards mild oxidation of sulfides to sulfones: efficient synthesis of diverse sulfonyl compounds

被引：13
作者：
Almeida, Renata G. [1 ]
de Carvalho, Renato L. [1 ]
Nunes, Mateus P. [1 ]
Gomes, Roberto S. [2 ]
Pedrosa, Leandro F. [3 ]
de Simone, Carlos A. [4 ]
Gopi, Elumalai [5 ]
Geertsen, Valerie [6 ]
Gravel, Edmond [5 ]
Doris, Eric [5 ]
da Silva Junior, Eufranio N. [1 ]
机构：
[1] Univ Fed Minas Gerais, Dept Chem, Inst Exact Sci, BR-31270901 Belo Horizonte, MG, Brazil
[2] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
[3] Fluminense Fed Univ, Volta Redonda, RJ, Brazil
[4] Univ Sao Paulo, Inst Phys, BR-13560160 Sao Carlos, SP, Brazil
[5] Univ Paris Saclay, CEA, SCBM, F-91191 Gif Sur Yvette, France
[6] CNRS, CEA, NIMBE, F-91191 Gif Sur Yvette, France
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2019年 / 9卷 / 11期
关键词：
SELECTIVE CATALYTIC-OXIDATION; TURN-ON; ALPHA; TRANSFORMATIONS; DERIVATIVES; INHIBITORS; LAPACHONE; QUINONES; SYSTEMS; DESIGN;
D O I：
10.1039/c9cy00384c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A heterogeneous catalyst was assembled with ruthenium nanoparticles on carbon nanotubes and used in a mild oxidation method to prepare sulfones from sulfides. The system proved very efficient on the investigated substrates and the products were obtained in high yields.
引用
收藏
页码：2742 / 2748
页数：7
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