Verdazyl radicals as redox-active, non-innocent, ligands: contrasting electronic structures as a function of electron-poor and electron-rich ruthenium bis(β-diketonate) co-ligands

被引：48

作者：

McKinnon, Stephen D. J. ^{[2
]}

Patrick, Brian O. ^{[3
]}

Lever, A. B. P. ^{[1
]}

Hicks, Robin G. ^{[2
]}

机构：

[1] York Univ, Dept Chem, N York, ON M3J 1P3, Canada

[2] Univ Victoria, Dept Chem, Victoria, BC, Canada

[3] Univ British Columbia, Dept Chem, Crystallog Lab, Vancouver, BC V6T 1Z1, Canada

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 05期

基金：

加拿大自然科学与工程研究理事会;

关键词：

ALCOHOLS INCLUDING METHANOL; TRANSITION-METAL-COMPLEXES; MAGNETIC-PROPERTIES; NITROXYL RADICALS; COORDINATION CHEMISTRY; GALACTOSE-OXIDASE; OXIDATION; ZIRCONIUM(IV); DIOXYGEN; SEMIQUINONE;

D O I：

10.1039/b919920a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spectroscopic, structural, and computational studies of verdazyl radical-ruthenium complexes reveal the verdazyl to be a redox-active and non-innocent ligand. The ensuing delocalization of charge is highly sensitive to the nature of the beta-diketonate co-ligands.

引用

页码：773 / 775

页数：3

共 49 条

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