Anionic [4+2]cycloaddition - Retro [4+2]cycloaddition strategy in the synthesis of psoralen and its isoster

被引：0

作者：

Bandyopadhyay, M ^{[1
]}

Datta, K ^{[1
]}

Mal, D ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 1999年 / 76卷 / 11-12期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Furan-1,4-dipolar agents 7 and 16e, prepared in few steps from commercially available furoates, have been annulated with bicyclopentadienone 2 to provide pentacyclic frameworks 8 and 17 respectively. Subsequent transformations of 8 and 17 through retro-Diels-Alder reaction and indenol-indanone rearrangement have furnished psoralen precursors 14 and 19. Similarly, oxaindacenone 23 has been prepared in good yield from 21.

引用

页码：551 / 556

页数：6

共 12 条

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