Metal complexes with the zwitterion 4-(trimethylammonio) benzenethiolate: Synthesis, structures and applications

被引：32

作者：

Bao, Shu-Jin ^{[1
]}

Liu, Chun-Yu ^{[1
]}

Zhang, Min ^{[1
]}

Chen, Xu-Ran ^{[1
]}

Yu, Hong ^{[1
]}

Li, Hong-Xi ^{[1
]}

Braunstein, Pierre ^{[3
]}

Lang, Jian-Ping ^{[1
,2
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[3] Univ Strasbourg, Inst Chim, UMR CNRS 7177, CS 90032, 4 Rue Blaise Pascal, F-67081 Strasbourg, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2019年 / 397卷

基金：

中国国家自然科学基金;

关键词：

Metal complex; 4-(Trimethylammonio)benzenethiolate; Synthesis; Structure; Reactivity; Application; C-S BOND; FERROUS FE4S4 CLUSTER; CRYSTAL-STRUCTURES; SOLID-STATE; THIOLATE COMPLEXES; COORDINATION POLYMERS; CHALCOGENIDE CLUSTERS; MOLECULAR-STRUCTURE; GOLD NANOPARTICLE; MERCURY THIOLATE;

D O I：

10.1016/j.ccr.2019.06.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review summarizes the syntheses, crystal structures and applications of metal complexes with a specific zwitterionic thiolate ligand, 4-(trimethylammonio)benzenethiolate (Tab). The chemistry of Tab with transition metals (Fe, Co, Ni, Pd, Cu, Ag, Au, Zn, Cd, Hg), main group metals (In, Pb, Bi) and in heterometallic systems is described. The most significant structural features of the metal/Tab complexes are summarized and trends are discussed as a function of nuclearity and coordination numbers. The reactivity of specific metal/Tab complexes towards N- and P- donor ligands, organic acids, inorganic anions and metal ions is discussed. The luminescence and dielectric properties of the metal/Tab complexes and their applications as fluorescent biosensors and precursors to metal nanoparticles and catalysts for organic transformations are also illustrated. (C) 2019 Elsevier B.V. All rights reserved.

引用

页码：28 / 53

页数：26

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