An Ultrafast Rechargeable Hybrid Sodium-Based Dual-Ion Capacitor Based on Hard Carbon Cathodes

被引:176
作者
Chen, Suhua [1 ]
Wang, Jue [1 ]
Fan, Ling [1 ]
Ma, Ruifang [1 ]
Zhang, Erjing [1 ]
Liu, Qian [1 ]
Lu, Bingan [1 ]
机构
[1] Hunan Univ, Sch Phys & Elect, State Key Lab Adv Design & Mfg Vehicle Body, Changsha 410082, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
hard carbon; hybrid sodium-based dual-ion hybrid capacitors; nitrogen-doped; soft carbon; PERFORMANCE SUPERCAPACITORS; POSITIVE ELECTRODE; GRAPHITIC CARBON; LITHIUM STORAGE; LI-ION; BATTERIES; ANODE; NITROGEN; INTERCALATION; NANOFIBERS;
D O I
10.1002/aenm.201800140
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hybrid sodium-based dual-ion capacitors (NDICs), which integrate the advantages of supercapacitors and sodium-ion batteries, have attracted tremendous attention recently. In this work, hybrid sodium-based dual-ion capacitors are successfully developed with nitrogen-doped microporous hard carbon as the cathode and soft carbon as the anode. N-doping is beneficial to the functional groups, porous structure, and electric conductivity of hard carbon. Hybrid NDICs possess a wide voltage range (0.01-4.7 V), high-energy density of 245.7 W h kg(-1) at a power density of 1626 W kg(-1), long cycle life (1000 cycles), and outstanding rate performance.
引用
收藏
页数:8
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