(E)-1-(4-Bromophenyl)-3-(2,4,6-trimethoxyphenyl)prop-2-en-1-one

被引:16
作者
Chantrapromma, Suchada [1 ]
Suwunwong, Thitipone [1 ]
Karalai, Chatchanok [1 ]
Fun, Hoong-Kun [2 ]
机构
[1] Prince Songkla Univ, Crystal Mat Res Unit, Dept Chem, Fac Sci, Hat Yai 90112, Songkhla, Thailand
[2] Univ Sains Malaysia, Xray Crystallog Unit, Sch Phys, George Town 11800, Malaysia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
X-RAY; DIFFRACTION; DYES;
D O I
10.1107/S1600536809010496
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The molecule of the title chalcone derivative, C(18)H(17)BrO(4), is twisted, the dihedral angle between the 4-bromophenyl and 2,4,6-trimethoxyphenyl rings being 39.17 (6)degrees. The three methoxy groups are oriented in two different conformations whereby two methoxy groups are coplanar, whereas the third is twisted with respect to the attached benzene ring [C-O-C-C torsion angles of -2.84 (18), -2.80 (18) and -9.31 (18)degrees]. Weak intramolecular C-H center dot center dot center dot O interactions generate two S(5) and one S(6) ring motifs. In the crystal structure, molecules are linked into supramolecular sheets parallel to the bc plane by weak C-H center dot center dot center dot O interactions. These sheets are stacked along the a axis. The crystal structure is further stabilized by weak C-H center dot center dot center dot pi interactions.
引用
收藏
页码:O893 / U3178
页数:12
相关论文
共 13 条
[1]   TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].
ALLEN, FH ;
KENNARD, O ;
WATSON, DG ;
BRAMMER, L ;
ORPEN, AG ;
TAYLOR, R .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19
[2]   PATTERNS IN HYDROGEN BONDING - FUNCTIONALITY AND GRAPH SET ANALYSIS IN CRYSTALS [J].
BERNSTEIN, J ;
DAVIS, RE ;
SHIMONI, L ;
CHANG, NL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (15) :1555-1573
[3]  
Bruker, 2005, APEX2 SAINT SADABS
[4]   A NITROGEN-GAS-STREAM CRYOSTAT FOR GENERAL X-RAY-DIFFRACTION STUDIES [J].
COSIER, J ;
GLAZER, AM .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1986, 19 (02) :105-107
[5]   Dual emission of chalcone-analogue dyes emitting in the red region [J].
Fayed, TA ;
Awad, MK .
CHEMICAL PHYSICS, 2004, 303 (03) :317-326
[6]   Ferrocenyl chalcones containing anthracenyl group: Synthesis, X-ray crystal structures and electrochemical properties [J].
Jung, YounJung ;
Son, Kyung-In ;
Oh, Youl Eui ;
Noh, Dong-Youn .
POLYHEDRON, 2008, 27 (02) :861-867
[7]   Crystal growth of 2,4,5-Trimethoxy-4′-chlorochalcone and its characterization [J].
Patil, P. S. ;
Dhannaprakash, S. M. .
MATERIALS LETTERS, 2008, 62 (03) :451-453
[8]  
Prasad YR, 2008, ARKIVOC, P266
[9]   FLUORESCENCE QUANTUM YIELD OF OXAZINE AND CARBAZINE LASER-DYES [J].
SENS, R ;
DREXHAGE, KH .
JOURNAL OF LUMINESCENCE, 1981, 24-5 (NOV) :709-712
[10]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122