Hydrogenation of various organic substrates using polystyrene anchored orthometallated ruthenium (II) complex as catalyst

被引：24

作者：

Islam, S. M. ^{[1
]}

Tuhina, K.

Mubarak, M. ^{[1
]}

Mondal, P. ^{[1
]}

机构：

[1] Univ Kalyani, Dept Chem, Nadia 741235, W Bengal, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2009年 / 297卷 / 01期

关键词：

Hydrogenation; Polymer anchored; Orthometallated ruthenium (II) complex; Nitroorganics; Alkenes; Nitriles; Ketones; DIHYDROGEN REDUCTION; EFFICIENT; PALLADIUM(II); OXIDATION; SUZUKI;

D O I：

10.1016/j.molcata.2008.09.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic activity of orthometallated complex [Ru(azb)(CO)(2)Cl](2) (Hazb=azobenzene) anchored to macroporous polystyrene beads was investigated towards the reduction of organic nitrocompounds, alkenes, alkynes, nitriles, Schiff bases, ketones and aldehydes under high pressure, high temperature conditions in mild coordinating media. Comparative studies have been done with the corresponding unsupported metal complexes. The polymer catalyst was found to be comparable to its homogeneous counterpart in activity and product selectivity but superior in stability and reusability. A tentative reduction mechanism was proposed on the basis of kinetic studies and the isolation of reactive intermediates. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：18 / 25

页数：8

共 39 条

[1] Cerium incorporated ordered manganese oxide OMS-2 materials: Improved catalysts for wet oxidation of phenol compounds [J].

Abecassis-Wolfovich, M ;

Jothiramalingam, R ;

Landau, MV ;

Herskowitz, M ;

Viswanathan, B ;

Varadarajan, TK .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2005, 59 (1-2) :91-98

[2] Catalytic activity of polymer-montmorillonite composites in chemical reactions [J].

Akelah, A. ;

Rehab, A. ;

Kenawy, E. -R. ;

Abou Zeid, M. S. .

JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 101 (02) :1121-1129

[3]

ASTORGA NM, 2006, J MOL CATAL A-CHEM, V247, P145

[4] ORTHOMETALATED PALLADIUM(II) COMPLEX-CATALYZED REDUCTION OF NITROALKANES AND NITRILES [J].

BOSE, A ;

SAHA, CR .

JOURNAL OF MOLECULAR CATALYSIS, 1989, 49 (03) :271-283

[5] METAL-SUPPORT INTERACTION EFFECTS IN THE LIQUID-PHASE SELECTIVE HYDROGENATION OF 1,4-BUTYNEDIOL WITH NICKEL-CATALYSTS SUPPORTED ON ALPO4 AND ON OTHER CONVENTIONAL NON-REDUCIBLE COMPOUNDS [J].

CAMPELO, JM ;

GUARDENO, R ;

LUNA, D ;

MARINAS, JM ;

MORALES, J ;

TIRADO, JL .

JOURNAL OF MOLECULAR CATALYSIS, 1993, 85 (03) :305-325

[6] WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .4. CATALYTIC-HYDROGENATION OF ALDEHYDES IN AN AQUEOUS 2-PHASE SOLVENT SYSTEM USING A 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE COMPLEX OF RUTHENIUM [J].

DARENSBOURG, DJ ;

JOO, F ;

KANNISTO, M ;

KATHO, A ;

REIBENSPIES, JH ;

DAIGLE, DJ .

INORGANIC CHEMISTRY, 1994, 33 (02) :200-208

[7] Polymer supported catalysts for oxidation of phenol and cyclohexene using hydrogen peroxide as oxidant [J].

Gupta, K. C. ;

Sutar, A. K. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 280 (1-2) :173-185

[8] PREPARATIONS AND CHARACTERIZATION OF CYCLORUTHENATED COMPLEXES DERIVED FROM 1-PHENYLPYRAZOLE, 2-PHENYLPYRIDINE, AND BENZO[H]QUINOLINE [J].

HIRAKI, K ;

OBAYASHI, Y ;

OKI, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1979, 52 (05) :1372-1376

[9] GAS-PHASE HYDROGENATION OF ACETONITRILE ON RANEY-NICKEL CATALYSTS - REACTIVE HYDROGEN [J].

HOCHARD, F ;

JOBIC, H ;

MASSARDIER, J ;

RENOUPREZ, AJ .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 95 (02) :165-172

[10] Reductive carbonylation of nitroaromatics using RhA(CO)2 [J].

Islam, SM ;

Mal, D ;

Palit, BK ;

Saha, CR .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 142 (02) :169-181

← 1 2 3 4 →