Crystal engineering of hybrid inorganic-organic systems based upon complexes with dissymmetric compartmental ligands

被引：108

作者：

Andruh, Marius ^{[1
]}

Branzea, Diana G. ^{[1
]}

Gheorghe, Ruxandra ^{[1
]}

Madalan, Augustin M. ^{[1
]}

机构：

[1] Univ Bucharest, Inorgan Chem Lab, Fac Chem, Bucharest 020464, Romania

来源：

CRYSTENGCOMM | 2009年 / 11卷 / 12期

关键词：

SOLID-STATE ARCHITECTURES; PI-PI-STACKING; 2D COORDINATION POLYMER; MAGNETIC-PROPERTIES; 2ND-SPHERE COORDINATION; METAL-COMPLEXES; HETEROBINUCLEAR COMPLEXES; BUILDING-BLOCKS; 3D-4F COMPLEXES; HYDROGEN-BONDS;

D O I：

10.1039/b909476h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper illustrates the versatility of mono- and heterobinuclear complexes with dissymmetric compartmental ligands in designing molecular and supramolecular heterometallic systems. Mononuclear complexes with side-off bicompartmental ligands derived from o-vanillin act efficiently, through their empty compartment, as hydrogen-bond receptors and as second coordination sphere ligands. These Schiff-bases are also suitable for synthesizing 3d-3d' and 3d-4f heterobinuclear complexes. Both 3d-3d' and 3d-4f complexes can be employed as nodes in obtaining coordination polymers with various dimensionalities and network topologies, as well as interesting magnetic and optical properties.

引用

页码：2571 / 2584

页数：14

共 75 条

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