Elemental phosphorus in strongly basic media as phosphorylating reagent: a dawn of halogen-free 'green' organophosphorus chemistry

被引：97

作者：

Trofimov, Boris A. ^{[1
]}

Gusarova, Nina K. ^{[1
]}

机构：

[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia

来源：

MENDELEEV COMMUNICATIONS | 2009年 / 19卷 / 06期

关键词：

TERTIARY PHOSPHINE OXIDES; ONE-POT SYNTHESIS; P-P BONDS; RED PHOSPHORUS; SUPERBASIC SYSTEMS; 4-VINYLBENZYL CHLORIDE; SECONDARY PHOSPHINES; CONVENIENT SYNTHESIS; RADICAL-ADDITION; DEFECT FORMATION;

D O I：

10.1016/j.mencom.2009.11.001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The elemental phosphorus/strong bases systems are gaining a growing attention as halogen-free 'green' phosphorylating reagents enabling a great variety of alkenes, acetylenes, organic halides and oxiranes to be converted in one-pot procedures to inaccessible primary, secondary and tertiary phosphines and phosphine oxides.

引用

页码：295 / 302

页数：8