Degradation mechanism of 6063 aluminium matrix composite reinforced with TiC and Al2O3 particles

被引:52
作者
Ao, Min [1 ,2 ]
Liu, Huimin [1 ]
Dong, Chaofang [2 ]
Feng, Shan [1 ]
Liu, Juncheng [1 ]
机构
[1] Inner Mongolia Univ Technol, Sch Mat Sci & Engn, Inner Mongolia Key Lab Light Met Mat, Hohhot 010051, Peoples R China
[2] Univ Sci & Technol Beijing, Corros & Protect Ctr, Key Lab Corros & Protect MOE, Beijing 100083, Peoples R China
关键词
Aluminium matrix composites; Corrosion behaviour; Reinforcing particles; Density function theory;
D O I
10.1016/j.jallcom.2020.157838
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The degradation mechanism of 6063 aluminium matrix composites reinforced with TiC and Al2O3 particles was investigated by microstructure characterization, electrochemical experiments, scanning Kelvin probe force microscopy (SKPFM) and density function theory (DFT) calculation. The addition of the TiC and Al2O3 particles refines the grain structure of the composite material and increases the content of AlFeSi phase at the grain boundary. The surface Volta potential of AlFeSi (653 mV) was higher than that of the matrix alloy and Cl- is more easily adsorbed on the surface of AlFeSi phase rather than on TiC particles and AlMgSiCu phase. The strong absorption energy between Cl- and the AlFeSi phase will destroy the surrounding oxide film and cause the pitting corrosion around the AlSiFe phase. Therefore, the adding of TiC and Al2O3 particles reduces the corrosion resistance of the composite material. (C) 2020 Elsevier B.V. All rights reserved.
引用
收藏
页数:11
相关论文
共 56 条
[11]   Composites fabricated by self-propagating high-temperature synthesis [J].
Fu, ZY ;
Wang, H ;
Wang, WM ;
Yuan, RZ .
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2003, 137 (1-3) :30-34
[12]   Preparation of in-situ TiB2 and Mg2Si hybrid particulates reinforced Al-matrix composites [J].
Gao, Qi ;
Wu, Shusen ;
Lu, Shulin ;
Duan, Xuecheng ;
Zhong, Zhiyuan .
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 651 :521-527
[13]   Effects of nanosized TiC and TiB2 particles on the corrosion behavior of Al-Mg-Si alloy [J].
Geng, Run ;
Jia, Si-Qi ;
Qiu, Feng ;
Zhao, Qing-Long ;
Jiang, Qi-Chuan .
CORROSION SCIENCE, 2020, 167
[14]   Effects of hybrid processing on microstructural and mechanical properties of thixoformed aluminum matrix composite [J].
Hanizam, H. ;
Salleh, M. S. ;
Omar, M. Z. ;
Sulong, A. B. ;
Arif, M. A. M. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 836
[15]   ESCA, XRD, AND IR CHARACTERIZATION OF ALUMINUM-OXIDE, HYDROXYFLUORIDE, AND FLUORIDE SURFACES IN CORRELATION WITH THEIR CATALYTIC ACTIVITY IN HETEROGENEOUS HALOGEN EXCHANGE-REACTIONS [J].
HESS, A ;
KEMNITZ, E ;
LIPPITZ, A ;
UNGER, WES ;
MENZ, DH .
JOURNAL OF CATALYSIS, 1994, 148 (01) :270-280
[16]   STRUCTURAL INVESTIGATION OF ALPHA-AL2O3 AT 2170-K [J].
ISHIZAWA, N ;
MIYATA, T ;
MINATO, I ;
MARUMO, F ;
IWAI, S .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (FEB) :228-230
[17]  
Jifeng Zhang, 2020, MAT SCI ENG, V794
[18]   The role of microstructure and microchemistry on intergranular corrosion of aluminium alloy AA7085-T7452 [J].
Kairy, S. K. ;
Turk, S. ;
Birbilis, N. ;
Shekhter, A. .
CORROSION SCIENCE, 2018, 143 :414-427
[19]   Salt spray corrosion and electrochemical corrosion properties of anodic oxide film on 7475 aluminum alloy [J].
Kong Dejun ;
Wang Jinchun .
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 632 :286-290
[20]   Aluminium reinforced by WC and TiC nanoparticles (ex-situ) and aluminide particles (in-situ): Microstructure, wear and corrosion behaviour [J].
Lekatou, A. ;
Karantzalis, A. E. ;
Evangelou, A. ;
Gousia, V. ;
Kaptay, G. ;
Gacsi, Z. ;
Baumli, P. ;
Simon, A. .
MATERIALS & DESIGN, 2015, 65 :1121-1135