MOF-Graphite Oxide Composites: Combining the Uniqueness of Graphene Layers and Metal-Organic Frameworks

被引：583
作者：
Petit, Camille
Bandosz, Teresa J. [1 ]
机构：
[1] CUNY City Coll, Dept Chem, New York, NY 10031 USA
来源：
ADVANCED MATERIALS | 2009年 / 21卷 / 46期
基金：
美国国家科学基金会;
关键词：
PORE-SIZE; DESIGN; ADSORPTION; AMMONIA; FLEXIBILITY; ADSORBENTS; DYNAMICS; SORPTION; STORAGE; WATER;
D O I：
10.1002/adma.200901581
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nanocomposites containing graphite oxide (GO) and metal-organic frameworks (MOFs) are prepared. They have a well-defined structure, in which graphene layers from GO alternate with layers of MOF via linkages between epoxy groups from Go and zinc oxide from the MOF (see image). The enhanced porosity and dispersive forces of the composites compared to the precursors provide views for applications in gas adsorption.
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收藏
页码：4753 / +
页数：6
相关论文
共 37 条
[1]   Metal-organic frameworks with high capacity and selectivity for harmful gases [J].
Britt, David ;
Tranchemontagne, David ;
Yaghi, Omar M. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (33) :11623-11627
[2]  
Brodie B., 1860, ANN CHIM PHYS, V59, P466
[3]   Water dynamics in graphite oxide investigated with neutron scattering [J].
Buchsteiner, Alexandra ;
Lerf, Anton ;
Pieper, Joerg .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (45) :22328-22338
[4]   Selective gas sorption within a dynamic metal-organic framework [J].
Chen, Banglin ;
Ma, Shengqian ;
Hurtado, Eric J. ;
Lobkovsky, Emil B. ;
Liang, Chengdu ;
Zhu, Haoguo ;
Dai, Sheng .
INORGANIC CHEMISTRY, 2007, 46 (21) :8705-8709
[5]   Preparation and characterization of graphene oxide paper [J].
Dikin, Dmitriy A. ;
Stankovich, Sasha ;
Zimney, Eric J. ;
Piner, Richard D. ;
Dommett, Geoffrey H. B. ;
Evmenenko, Guennadi ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2007, 448 (7152) :457-460
[6]   Highly porous and stable metal-organic frameworks: Structure design and sorption properties [J].
Eddaoudi, M ;
Li, HL ;
Yaghi, OM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (07) :1391-1397
[7]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[8]   The interaction of water with MOF-5 simulated by molecular dynamics [J].
Greathouse, Jeffery A. ;
Allendorf, Mark D. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (33) :10678-10679
[9]   Tailoring the dimensionality of metal-organic frameworks incorporating Pt and Pd. From molecular complexes to 3D networks [J].
Hafizovic, Jasmina ;
Krivokapic, Alexander ;
Szeto, Kai C. ;
Jakobsen, Soren ;
Lillerud, Karl Petter ;
Olsbye, Unni ;
Tilset, Mats .
CRYSTAL GROWTH & DESIGN, 2007, 7 (11) :2302-2304
[10]   The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities [J].
Hafizovic, Jasmina ;
Bjorgen, Morten ;
Olsbye, Unni ;
Dietzel, Pascal D. C. ;
Bordiga, Silvia ;
Prestipino, Carmelo ;
Lamberti, Carlo ;
Lillerud, Karl Petter .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (12) :3612-3620
1234