Synthesis, characterization, and reactivity of cationic hydride [HPd(diphosphine)2]+CF3SO3-, the missing member of the family [HM(dppe)2]+X- (M=Ni, Pd, Pt).: DFT QM/MM structural predictions for the [HPd(dppe)2]+ moiety

被引：16

作者：

Aresta, M

Dibenedetto, A

Amodio, E

Pápai, I

Schubert, G

机构：

[1] Univ Bari, Dept Chem, I-70126 Bari, Italy

[2] Univ Bari, METEA Res Ctr, I-70126 Bari, Italy

[3] Hungarian Acad Sci, Chem Res Ctr, H-1525 Budapest, Hungary

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 25期

关键词：

D O I：

10.1021/ic020631p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, characterization, and properties of the cationic hydride [HPd(dppe)(2)]-CF3SO3-.1/8THF, the missing member of the family [HM(dppe)(2)]X-+(-) (M = Ni, Pd, Pt), are described. The Pd hydride is not stable in solution and may react as either a proton or a hydride donor. DFT QM/MM calculations of the [HPd(dppe)(2)](+) moiety have allowed us to predict its structure and reactivity.

引用

页码：6550 / 6552

页数：3

共 13 条

[1]

Aresta M, 2002, EUR J INORG CHEM, P2188

[2] TETRAPHENYLBORATE COORDINATION CHEMISTRY - SYNTHESIS, SOLID-STATE AND SOLUTION CHARACTERIZATION, AND PROPERTIES OF ([(C2H4)2RH(ETA(6)-PH)]2BPH2)O3SCF3 AND ([(C2H4)2RH(ETA(6)-PH)]3BPH)(O3SCF3)2 - THE 1ST EXAMPLES OF A TETRAPHENYLBORATE ANION ACTING AS A 12-E OR 18-E DONOR TO METAL CENTERS [J].