Novel nanocellulosic xylan composite film

被引:71
作者
Saxena, Amit [1 ]
Elder, Thomas J. [2 ]
Pan, Shaobo [1 ]
Ragauskas, Arthur J. [1 ,3 ]
机构
[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA
[2] US Forest Serv, USDA, So Res Stn, Pineville, LA 71360 USA
[3] Chalmers Univ Technol, SE-41296 Gothenburg, Sweden
关键词
Xylan; Film; Cellulose whiskers; Strength; Nanocomposites; CELLULOSE WHISKERS; MICROCRYSTALLINE CELLULOSE; BEHAVIOR; SURFACE;
D O I
10.1016/j.compositesb.2009.05.003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanocellulosic-xylan films were prepared employing oat spelt xylan, cellulose whiskers and a plasticizer. The mechanical properties of the films were evaluated using tensile testing under controlled temperature and humidity conditions. The tensile data showed that the addition of sulfonated cellulose whiskers lead to a substantial improvement in strength properties. Addition of 7 wt% of sulfonated whiskers increased the tensile energy absorption of xylan films by 445% and the tensile strength of the film by 141%. Furthermore, films to which 7% cellulose whiskers were added showed that nanocellulose whiskers produced with sulfuric acid (sulfonated whiskers) were significantly better at increasing film strength than cellulose whiskers produced by hydrochloric acid hydrolysis of cellulosic fibers. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:727 / 730
页数:4
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