The configurational assignment of the optically active 5-(1-hydroperoxyethyl)-3-ethoxycarbonyl-2-methylfuran and its alcohol by exciton-coupled circular dichroism (ECCD)

被引：11

作者：

Adam, W ^{[1
]}

Humpf, HU ^{[1
]}

Korb, MN ^{[1
]}

Schreier, P ^{[1
]}

机构：

[1] UNIV WURZBURG,INST FOOD CHEM,D-97074 WURZBURG,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 21期

关键词：

D O I：

10.1016/S0957-4166(97)00515-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The absolute configuration of the furan-derived hydroperoxide land its alcohol 2, readily available in optically active form by kinetic resolution of the racemic hydroperoxide with horseradish peroxidase (HRP), was determined by the exciton-coupled circular dichroism (ECCD) method on their 2-naphthoate derivatives 4. (C) 1997 Elsevier Science Ltd.

引用

页码：3555 / 3558

页数：4

共 11 条

[1] The titanium-catalyzed, asymmetric epoxidation of allylic alcohols with optically active hydroperoxides in the presence of achiral diol ligands [J].