Small-angle neutron scattering from samples of expanded carbon

被引:7
作者
Bogdanov, S. G.
Valiev, E. Z.
Dorofeev, Yu. A.
Pirogov, A. N.
Skryabin, Yu. N.
Makotchenko, V. G.
Nazarov, A. S.
Fedorov, V. E.
机构
[1] Russian Acad Sci, Ural Div, Inst Met Phys, Ekaterinburg 620041, Russia
[2] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
关键词
61.12.-g;
D O I
10.1134/S1063774506070030
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The subatomic structure of expanded graphite has been investigated by small-angle neutron scattering. Samples were synthesized during quick thermal decomposition of intercalated compounds based on oxidized graphite. They had a low bulk density (up to 0.1 g/cm(3)) and were characterized by considerable small-angle scattering. It has been established that majority of the volume of expanded graphite samples is occupied by participles with characteristic sizes in two ranges: from 6 to 8 nm and from 20 to 30 nm. Small particles have properties of a surface fractal with the dimension D-s = 2.4-2.6, whereas the larger particles are mainly smooth and have the dimension D-s = 2.0-2.1. The specific surface of the samples studied was determined from the small-angle scattering data.
引用
收藏
页码:S12 / S15
页数:4
相关论文
共 10 条
[1]   SMALL-ANGLE X-RAY-SCATTERING INVESTIGATION OF SUBMICROSCOPIC POROSITY WITH FRACTAL PROPERTIES [J].
BALE, HD ;
SCHMIDT, PW .
PHYSICAL REVIEW LETTERS, 1984, 53 (06) :596-599
[2]   SCATTERING BY AN INHOMOGENEOUS SOLID .2. THE CORRELATION FUNCTION AND ITS APPLICATION [J].
DEBYE, P ;
ANDERSON, HR ;
BRUMBERGER, H .
JOURNAL OF APPLIED PHYSICS, 1957, 28 (06) :679-683
[3]  
Lukashin AV, 1999, DOKL AKAD NAUK+, V369, P781
[4]   X-RAY POWDER DIFFRACTION STUDY OF POLY(CARBON MONOFLUORIDE), CF1.12 [J].
MAHAJAN, VK ;
BADACHHAPE, RB ;
MARGRAVE, JL .
INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1974, 10 (12) :1103-1109
[5]  
Nazarov A. S., 2002, IAN SSSR NEORG MATER, V38, P351
[6]  
SCHAEFER DW, 1988, FRACTALS PHYS
[7]  
Svergun D. I., 1986, XRAY NEUTRON SMALL A
[8]   Structural state of expanded graphite prepared from intercalation compounds [J].
Teplykh, A. E. ;
Bogdanov, S. G. ;
Dorofeev, Yu. A. ;
Pirogov, A. N. ;
Skryabin, Yu. N. ;
Makotchenko, V. G. ;
Nazarov, A. S. ;
Fedorov, V. E. .
CRYSTALLOGRAPHY REPORTS, 2006, 51 (Suppl 1) :S62-S66
[9]  
Valiev E. Z., 2002, POVERKHNOST, P59
[10]  
Valiev E. Z., 2001, POVERKHNOST, P38