Carbon dioxide-promoted palladium-catalyzed dehydration of primary allylic alcohols: access to substituted 1,3-dienes

被引：15

作者：

Huang, Yan-Kai ^{[1
]}

Zhang, Wen-Zhen ^{[1
]}

Zhang, Ke ^{[1
]}

Wang, Wen-Le ^{[1
]}

Lu, Xiao-Bing ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2021年 / 8卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Carbon dioxide;

D O I：

10.1039/d0qo01465f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,3-Dienes are versatile synthons and important monomers. Herein we report a carbon dioxide promoted dehydration reaction of primary allylic alcohols to produce substituted 1,3-dienes in good yields. Taking advantage of carbon dioxide as a promoter to facilitate the alcoholic C-O bond cleavage via the formation of an allylic bicarbonate ester, this reaction proceeds under mild conditions.

引用

页码：941 / 946

页数：6

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