Carbon dioxide-promoted palladium-catalyzed dehydration of primary allylic alcohols: access to substituted 1,3-dienes

被引：15
作者：
Huang, Yan-Kai [1 ]
Zhang, Wen-Zhen [1 ]
Zhang, Ke [1 ]
Wang, Wen-Le [1 ]
Lu, Xiao-Bing [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2021年 / 8卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Carbon dioxide;
D O I：
10.1039/d0qo01465f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1,3-Dienes are versatile synthons and important monomers. Herein we report a carbon dioxide promoted dehydration reaction of primary allylic alcohols to produce substituted 1,3-dienes in good yields. Taking advantage of carbon dioxide as a promoter to facilitate the alcoholic C-O bond cleavage via the formation of an allylic bicarbonate ester, this reaction proceeds under mild conditions.
引用
收藏
页码：941 / 946
页数：6
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