Electrochemically generated tungsten-based active species as catalysts for metathesis-related reactions:: 1.: Acyclic diene metathesis polymerization of 1,9-decadiene

被引：12

作者：

Dereli, O ^{[1
]}

Düz, B ^{[1
]}

Zümreoglu-Karan, B ^{[1
]}

Imamoglu, Y ^{[1
]}

机构：

[1] Hacettepe Univ, Dept Chem, TR-06532 Ankara, Turkey

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2003年 / 17卷 / 01期

关键词：

ADMET; metathesis; catalyst; WCl6; 1,9-decadiene; polymerization; electrochemistry;

D O I：

10.1002/aoc.390

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The application of the WCl6-e(-)-Al-CH2Cl2 System to acyclic diene metathesis polymerization of 1,9-decadiene is reported. The polyoctenamer formed is of a weight-average molecular weight of 9000 with a polydispersity of 1.92. IR and NMR spectral analyses indicate the retention of the double bonds in the polymer structure with high trans content as expected from a step condensation reaction. This relatively stable catalytic system, however, also activates the competing vinyl addition reactions while being inactive in ring-closure metathesis reactions. Copyright (C) 2002 John Wiley Sons, Ltd.

引用

页码：23 / 27

页数：5

共 20 条

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