C-H hetero-functionalization of arenes through palladacyclopentane-type intermediates

被引：28
作者：
Cao, Liming [1 ]
Hua, Yu [1 ]
Cheng, Hong-Gang [1 ]
Zhou, Qianghui [1 ,2 ]
机构：
[1] Wuhan Univ, Sauvage Ctr Mol Sci, Engn Res Ctr Organosilicon Cpds & Mat, Minist Educ,Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
[2] Wuhan Univ, Inst Adv Studies, Wuhan 430072, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2021年 / 8卷 / 14期
基金：
中国国家自然科学基金;
关键词：
CROSS-COUPLING REACTIONS; PALLADIUM-CATALYZED ALKYLATION; ARYL IODIDES; BOND FUNCTIONALIZATION; OXIDATIVE ADDITION; NATURAL-PRODUCTS; AMINATION; ACTIVATION; NORBORNENE; HALIDES;
D O I：
10.1039/d0qo01350a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recent years have witnessed palladium-catalyzed C-H activation emerging as a versatile strategy for the construction of valuable scaffolds. Palladacyclopentane-type intermediates, usually created by C-H activation from an aryl-Pd(ii) precursor, provide opportunities for subsequent C-H hetero-functionalizations and have therefore received much attention in organic synthesis. In this review article, we summarise recent advances in the C-H hetero-functionalization of arenes through palladacyclopentane-type intermediates over the past decade.
引用
收藏
页码：3883 / 3914
页数：32
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