Corrosion behavior of steel in alkali-activated fly ash mortars in the light of their microstructural, mechanical and chemical characterization

被引:105
作者
Monticelli, C. [1 ]
Natali, M. E. [2 ]
Balbo, A. [1 ]
Chiavari, C. [3 ]
Zanotto, F. [4 ]
Manzi, S. [2 ]
Bignozzi, M. C. [2 ]
机构
[1] Univ Ferrara, Ctr Studi Corros & Met A Dacco, Via Saragat 1, I-44122 Ferrara, Italy
[2] Univ Bologna, Dipartimento Ingn Civile Chim Ambientale & Mat, Via Terracini 28, I-40131 Bologna, Italy
[3] Univ Bologna, CIRI MAM, Viale Risorgimento 2, I-40136 Bologna, Italy
[4] Univ Ferrara, Terra & Acqua Tech, Via Saragat 1, I-44122 Ferrara, Italy
关键词
Alkali activated cement; Corrosion; Chloride; Mechanical properties; Microstructure; CHLORIDE; CONCRETE; GEOPOLYMERS; TECHNOLOGY; DURABILITY; STRENGTH; PASTES; CEMENT;
D O I
10.1016/j.cemconres.2015.11.001
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
This study concerns the corrosion behavior of steel in different room temperature cured alkali-activated fly ash mortars exposed to chloride solution. The corrosion process was monitored by polarization resistance and corrosion potential measurements and the results were interpreted in the light of a complete microstructural, mechanical and chemical characterization of the mortars. The most compact alkali-activated mortars have higher porosity and lower mechanical properties than a cement-based mortar (CEM), but the protectiveness afforded to the rebars is slightly higher than that obtained in CEM. The reason for this discrepancy is connected to a lower chloride content accumulated in the former mortar type and to a specific inhibition of the rebar corrosion afforded by the pore electrolyte in alkali-activated mortars. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:60 / 68
页数:9
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