Tetrakis(6-methyl-2,2′-bipyridine)-1κ2N,N′;2κ2N,N′;3κ2N,N′;4κ2N,N′-tetra-μ-nitrato-1:2κ2O:O′;2:3κ3O:O′,O";2:3κ3O,O′:O";3:4κ2O:O′-tetranitrato-1κ4O,O′;4κ2O,O′-tetralead(II)

被引：22

作者：

Ahmadi, Roya ^{[2
]}

Kalateh, Khadijeh ^{[2
]}

Alizadeh, Robabeh ^{[1
]}

Khoshtarkib, Zeinab ^{[2
]}

Amani, Vahid ^{[2
]}

机构：

[1] Damghan Univ Basic Sci, Sch Chem, Damghan, Iran

[2] Islamic Azad Univ, Shahr E Rey Branch, Tehran, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

D O I：

10.1107/S160053680903459X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the tetranuclear centrosymmetric title compound, [Pb-4(NO3)(8)(C11H10N2)(4)], irregular PbN2O5 and PbN2O4 coordination polyhedra occur. The heptacoordinated lead(II) ion is bonded to two bidentate and one monodentate nitrate ion and one bidentate 6-methyl-2,2'-bipyridine (mbpy) ligand. The six-coordinate lead(II)ion is bonded to one bidentate and two monodentate nitrate anions and one mbpy ligand. In the crystal, bridging nitrate anions lead to infinite chains propagating in [111]. A number of C-H center dot center dot center dot O hydrogen bonds may stabilize the structure.

引用

页码：M1169 / +

页数：13

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