Wide bandgap BaSnO3 films with room temperature conductivity exceeding 104 S cm -1

被引:192
作者
Prakash, Abhinav [1 ]
Xu, Peng [1 ]
Faghaninia, Alireza [2 ]
Shukla, Sudhanshu [3 ,4 ]
Ager, Joel W., III [3 ,5 ]
Lo, Cynthia S. [2 ]
Jalan, Bharat [1 ]
机构
[1] Univ Minnesota Twin Cities, Chem Engn & Mat Sci, Minneapolis, MN 55455 USA
[2] Washington Univ, Dept Energy Environm & Chem Engn, St Louis, MO 63130 USA
[3] Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA
[4] Nanyang Technol Univ, Energy Res Inst, Interdisciplinary Grad Sch, Sch Mat Sci & Engn, 50 Nanyang Ave, Singapore 639798, Singapore
[5] Univ Calif Berkeley, Mat Sci & Engn, Berkeley, CA 94720 USA
来源
NATURE COMMUNICATIONS | 2017年 / 8卷
基金
新加坡国家研究基金会; 美国国家科学基金会;
关键词
GAN;
D O I
10.1038/ncomms15167
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Wide bandgap perovskite oxides with high room temperature conductivities and structural compatibility with a diverse family of organic/inorganic perovskite materials are of significant interest as transparent conductors and as active components in power electronics. Such materials must also possess high room temperature mobility to minimize power consumption and to enable high-frequency applications. Here, we report n-type BaSnO3 films grown using hybrid molecular beam epitaxy with room temperature conductivity exceeding 10(4) S cm(-1). Significantly, these films show room temperature mobilities up to 120 cm(2) V-1 s(-1) even at carrier concentrations above 3-10(20) cm(-3) together with a wide bandgap (3 eV). We examine the mobility-limiting scattering mechanisms by calculating temperature-dependent mobility, and Seebeck coefficient using the Boltzmann transport framework and ab-initio calculations. These results place perovskite oxide semiconductors for the first time on par with the highly successful III-N system, thereby bringing all-transparent, high-power oxide electronics operating at room temperature a step closer to reality.
引用
收藏
页数:9
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