Synthesis and mesomorphic properties of a new series of triazole bent-core liquid crystalline molecules by "click" reaction

被引：1

作者：

Zhao, Yu-Zhen ^{[1
]}

He, Ze-Min ^{[1
]}

Chen, Gang ^{[2
]}

Miao, Zong-Cheng ^{[3
]}

Wang, Dong ^{[3
]}

Zhang, Hai-Quan ^{[1
]}

机构：

[1] Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao, Peoples R China

[2] Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China

[3] Univ Sci & Technol Beijing, Dept Mat Phys & Chem, Beijing 100083, Peoples R China

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2016年 / 624卷 / 01期

基金：

美国国家科学基金会;

关键词：

click reaction; mesomorphic behavior; Sonogashira coupling; triazole liquid-crystalline; Bent-core;

D O I：

10.1080/15421406.2015.1044713

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and mesomorphic properties of new triazole liquid-crystalline are presented and discussed. These triazole derivatives have been synthesized by reacting 4-hydrazoic iodobenzene with the 4-alkyl phenyl acetylene in dimethyl formamide (DMF). The molecular structure is characterized by 1H NMR, Fourier transform infrared spectroscopy (FTIR), time-of-flight mass spectrometry (TOF-MS) and the mesomorphic properties are characterized by polarizing optical microscope (POM) and (DSC). These new triazole liquid-crystallines have higher melting point and clearing point and the final compounds display both nematic and smectic liquid-crystalline phases.

引用

页码：171 / 179

页数：9

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