Synthesis of Dual-Size Cellulose-Polyvinylpyrrolidone Nanofiber Composites via One-Step Electrospinning Method for High-Performance Air Filter

被引:74
作者
Balgis, Ratna [1 ]
Murata, Hiroyuki [1 ]
Goi, Yohsuke [2 ]
Ogi, Takashi [1 ]
Okuyama, Kikuo [1 ]
Bao, Li [3 ]
机构
[1] Hiroshima Univ, Grad Sch Engn, Dept Chem Engn, 1-4-1 Kagamiyama, Higashihiroshima 7398527, Japan
[2] DKS Co Ltd, Minami Ku, 5 Ogawara Cho, Kyoto 6018391, Japan
[3] Nippon Muki Co Ltd, Nisshin Ueno Bldg,5-1-5 Higashi Ueno, Tokyo 1100015, Japan
关键词
FILTRATION; FIBERS; AEROSOL; NANOPARTICLES; ELIMINATION; MORPHOLOGY; MEMBRANES; FLOW; JET;
D O I
10.1021/acs.langmuir.7b01193
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dual-size nanofibers consisting of a random mixture of nano- and submicron-size nanofibers are promising structures for specific applications such as air filters because of their increased specific surface area and low pressure drop. Synthesis of dual-size nanofibers using one-step electrospinning was reported here for the first time. The formation of well-mixed nano- and submicron-size cellulose polyvinylpyrrolidone nanofiber composites was accomplished utilizing the physical properties of TEMPO-oxidized cellulose nanofibers (i.e., high thixotropy and high magnitude of zeta potential) and tuning the charge of the,polymer jet, which influences the formation and shape of Taylor cone, and Coulombic explosion. The dual-size nanofibers were then spun on the surface of a HEPA filter to obtain a multilayer air filter. Aerosol filtration measurements show that this multilayer air filter has an incredibly high performance, shown by the high quality factor (Qt), 0.117 Pa-1, which is 10 times the Qf of commercial HEPA filters.
引用
收藏
页码:6127 / 6134
页数:8
相关论文
共 31 条
[1]   Effect of viscosity, electrical conductivity, and surface tension on direct-current-pulsed drop-on-demand electrohydrodynamic printing frequency [J].
An, Seongpil ;
Lee, Min Wook ;
Kim, Na Young ;
Lee, Changmin ;
Al-Deyab, Salem S. ;
James, Scott C. ;
Yoon, Sam S. .
APPLIED PHYSICS LETTERS, 2014, 105 (21)
[2]   Synthesis and evaluation of straight and bead-free nanofibers for improved aerosol filtration [J].
Balgis, Ratna ;
Kartikowati, Christina W. ;
Ogi, Takashi ;
Gradon, Leon ;
Bao, Li ;
Seki, Kazuya ;
Okuyama, Kikuo .
CHEMICAL ENGINEERING SCIENCE, 2015, 137 :947-954
[3]   Verification of slip flow in nanofiber filter media through pressure drop measurement at low-pressure conditions [J].
Bao, Li ;
Seki, Kazuya ;
Niinuma, Hitoshi ;
Otani, Yoshio ;
Balgis, Ratna ;
Ogi, Takashi ;
Gradon, Leon ;
Okuyama, Kikuo .
SEPARATION AND PURIFICATION TECHNOLOGY, 2016, 159 :100-107
[4]  
Bognitzki M, 2001, ADV MATER, V13, P70, DOI 10.1002/1521-4095(200101)13:1<70::AID-ADMA70>3.3.CO
[5]  
2-8
[6]   Fabrication of Continuous Aligned Polyvinylpyrrolidone Fibers via Electrospinning by Elimination of the Jet Bending Instability [J].
Cui, Xiaojie ;
Li, Luming ;
Xu, Jun ;
Xu, Fu .
JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 116 (06) :3676-3681
[7]   Controlled deposition of electrospun poly(ethylene oxide) fibers [J].
Deitzel, JM ;
Kleinmeyer, JD ;
Hirvonen, JK ;
Tan, NCB .
POLYMER, 2001, 42 (19) :8163-8170
[8]   Bioinspired Ternary Artificial Nacre Nanocomposites Based on Reduced Graphene Oxide and Nanofibrillar Cellulose [J].
Duan, Jianli ;
Gong, Shanshan ;
Gao, Yuan ;
Xie, Xiaolin ;
Jiang, Lei ;
Cheng, Qunfeng .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (16) :10545-10550
[9]   Filtration of nano-aerosol using nanofiber filter under low Peclet number and transitional flow regime [J].
Hung, Chi-Ho ;
Leung, Wallace Woon-Fong .
SEPARATION AND PURIFICATION TECHNOLOGY, 2011, 79 (01) :34-42
[10]   Wood nanocelluloses: fundamentals and applications as new bio-based nanomaterials [J].
Isogai, Akira .
JOURNAL OF WOOD SCIENCE, 2013, 59 (06) :449-459