Magnetic and magnetocaloric properties of La0.7Ca0.3-xBaxMnO3 compounds

被引:143
|
作者
Phan, MH
Tian, SB
Yu, SC [1 ]
Ulyanov, AN
机构
[1] Chungbuk Natl Univ, Dept Phys, Cheongju 361763, South Korea
[2] Natl Acad Sci, Donetsk Physicotech Inst, UA-83114 Donetsk, Ukraine
关键词
magnetocaloric effect; entropy; refrigeration; perovskite manganite;
D O I
10.1016/S0304-8853(02)00584-X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Magnetic properties and magnetocaloric effect in La0.7Ca0.3-xBaxMnO3 (x = 0.12, 0.24, 0.3) compounds were investigated. It is shown that there is a large magnetic entropy change associated with the ferromagnetic-paramagnetic transition. The Curie temperature (T-C) increases with the barium addition, while the maximum entropy change (\DeltaS(M)(max)\) slightly decreases. La0.7Ca0.18Ba0.12MnO3 exhibits the largest \DeltaS(M)(max)\ value of 1.85 J/kg/K at 298 K among the compounds investigated Lip to 10kOe applied field. Through these results, La0.7Ca0.3-xBaxMnO3 materials are strongly suggested for the use of active refrigerants for magnetic refrigeration technology near and above room temperature. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:306 / 310
页数:5
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