IPSO-Hydroxylation of Boronic Acid via Ozonolysis: A Metal-, Ligand-, and Base-free Method

被引：18

作者：

Bommegowda, Yadaganahalli K. ^{[1
]}

Mallesha, Ningegowda ^{[2
]}

Vinayaka, Ajjampura C. ^{[1
]}

Sadashiva, Maralinganadoddi P. ^{[1
]}

机构：

[1] Univ Mysore, Dept Studies Chem, Mysuru, Karnataka, India

[2] R&D Ctr, Sri Ram Chem, Spl-52,Hebbal Ind Estate, Mysuru, Karnataka, India

来源：

CHEMISTRY LETTERS | 2016年 / 45卷 / 03期

关键词：

Alcohol; Boronic acid; Ozonolysis; ARYLBORONIC ACIDS; FREE OXIDATION; PHENOLS; CONVERSION; MILD; MECHANISMS; ESTERS;

D O I：

10.1246/cl.151087

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here, we have developed a simple, efficient, and metal-, ligand-, and base-free method for the synthesis of functionalized aryl and alicyclic alcohols via ozonolysis of corresponding boronic acids in aqueous ethanol. The procedure is compatible with a variety of functional groups and can be utilized as an alternative method for the synthesis of hydroxy arenes and alicyclic alcohols.

引用

页码：268 / 270

页数：3

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