Do hydroxyl radical-water clusters, OH(H2O)n, n=1-5, exist in the atmosphere?

被引：96

作者：

Allodi, Marco A. ^{[1
]}

Dunn, Meghan E. ^{[1
]}

Livada, Jovan ^{[1
]}

Kirschner, Karl N. ^{[1
]}

Shields, George C. ^{[1
]}

机构：

[1] Hamilton Coll, Dept Chem, Clinton, NY 13323 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2006年 / 110卷 / 49期

关键词：

D O I：

10.1021/jp064468l

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It has been speculated that the presence of OH (H2O) n clusters in the troposphere could have significant effects on the solar absorption balance and the reactivity of the hydroxyl radical. We have used the G3 and G3B3 model chemistries to model the structures and predict the frequencies of hydroxyl radical/water clusters containing one to five water molecules. The reaction between hydroxyl radical clusters and methane was examined as a function of water cluster size to gain an understanding of how cluster size affects the hydroxyl radical reactivity.

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页码：13283 / 13289

页数：7

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