Stepwise self-assembly of a discrete molecular honeycomb using a multitopic metallo-organic ligand

被引：19

作者：

Wu, Tun ^{[1
]}

Yuan, Jie ^{[1
]}

Song, Bo ^{[2
]}

Chen, Yu-Sheng ^{[3
]}

Chen, Mingzhao ^{[1
]}

Xue, Xiaobo ^{[1
]}

Liu, Qianqian ^{[1
]}

Wang, Jun ^{[1
]}

Chan, Yi-Tsu ^{[3
]}

Wang, Pingshan ^{[1
]}

机构：

[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China

[2] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[3] Natl Taiwan Univ, Dept Chem, 1,Sect 4 Roosevelt Rd, Taipei 10617, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 50期

基金：

中国国家自然科学基金;

关键词：

RING-IN-RING; TERPYRIDINE LIGANDS; SUPRAMOLECULAR CHEMISTRY; METAL CENTERS; ARCHITECTURES; COMPLEXES; GIANT; 2D; MACROMOLECULES; CUBOCTAHEDRON;

D O I：

10.1039/c7cc03715e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembly of a metallo-organic ligand, composed of an inner uncomplexed 120 degrees-bis(terpyridine) and an outer extended free 120 degrees-bis(terpyridine) linked by a triple <-tpy-Ru2+-tpy-> connector, and complexed with Zn2+, gave rise to a discrete planar supra-molecular honeycomb patterned fractal. The central metallo-hexagon was surrounded by six identical metallo-hexagons which perfectly mimicked the natural simple honeycomb structure.

引用

页码：6732 / 6735

页数：4

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