Methanol and Ethanol Electrooxidation on PtRu and PtNiCu as Studied by High-Resolution In Situ Electrochemical NMR Spectroscopy with Interdigitated Electrodes

被引：10

作者：

Sorte, Eric G. ^{[1
]}

Jilani, Safia ^{[1
]}

Tong, YuYe J. ^{[1
]}

机构：

[1] Georgetown Univ, Dept Chem, 37th & O St, Washington, DC 20057 USA

来源：

ELECTROCATALYSIS | 2017年 / 8卷 / 02期

关键词：

In situ high-resolution solution NMR; Fuel cell electrocatalysis; Reaction intermediates; Methanol oxidation; Ethanol oxidation; FUEL-CELLS;

D O I：

10.1007/s12678-016-0344-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Following a recent short communication (J. Electroanal. Chem. 769 (2016) 1-4) in which we demonstrated the feasibility and proof-of-concept results of using interdigitated metal electrodes to achieve high-resolution in situ electrochemical solution NMR for studying electrochemically driven reactions such as those involved in electrolysis and electrocatalysis, we report herein a more detailed technical description of the technique and its application to studying methanol and ethanol electrooxidation on PtRu and PtNiCu electrocatalysts.

引用

页码：95 / 102

页数：8

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