Fluorescence behaviors of metal complexes/PVC composites

被引：5
作者：
Fan, Chenxi [1 ]
Cui, Yongyan [1 ]
机构：
[1] Tianjin Univ Sci & Technol, Coll Chem Engn & Mat, Tianjin 300457, Peoples R China
来源：
MACROMOLECULAR RESEARCH | 2017年 / 25卷 / 04期
关键词：
composite; thin films; metal complexes; fluorescence; polyvinyl chloride (PVC);
D O I：
10.1007/s13233-017-5047-3
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
16 kinds of metal complexes were synthesized using ZnCl2, AlCl3, BiCl3, EuCl3, and ligands of 1,10-phenanthroline (phen), salicylic acid (Hsal) and 8-hydroxyquinoline (Oxin). Then metal complexes/polyvinyl chloride (PVC) composite thin films were produced using melt blending method with metal complexes and PVC resin as raw materials. The optimal addition ratio was obtained by changing the dosage of metal complexes. Fluorescence excitation and emission spectrum of metal complexes and the produced thin films were also investigated by thermogravimetric analysis (TG), fluorescence spectrum, transmissivity and haze test and tensile test. All the complexes show luminescent emissions in the solid phase.
引用
收藏
页码：357 / 364
页数：8
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