A triptycene-based polymer of intrinsic microposity that displays enhanced surface area and hydrogen adsorption

被引:266
作者
Ghanem, Bader S.
Msayib, Kadhum J.
McKeown, Neil B. [1 ]
Harris, Kenneth D. M.
Pan, Zhigang
Budd, Peter M.
Butler, Anna
Selbie, James
Book, David
Walton, Allan
机构
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales
[2] Univ Manchester, Sch Chem, Organ Mat Innovat Ctr, Manchester M13 9PL, Lancs, England
[3] Univ Birmingham, Dept Met & Mat, Sch Engn, Birmingham B15 2TT, W Midlands, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1039/b614214a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel triptycene-based polymer of intrinsic microporosity (Trip-PIM) displays enhanced surface area (1065 m(2) g(-1)) and reversibly adsorbs 1.65% hydrogen by mass at 1 bar/77 K and 2.71% at 10 bar/77 K.
引用
收藏
页码:67 / 69
页数:3
相关论文
共 30 条
[1]   Hydrogen adsorption on a single-walled carbon nanotube material:: a comparative study of three different adsorption techniques [J].
Ansón, A ;
Benham, M ;
Jagiello, J ;
Callejas, MA ;
Benito, AM ;
Maser, WK ;
Züttel, A ;
Sudan, P ;
Martínez, MT .
NANOTECHNOLOGY, 2004, 15 (11) :1503-1508
[2]   Free volume and intrinsic microporosity in polymers [J].
Budd, PM ;
McKeown, NB ;
Fritsch, D .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (20) :1977-1986
[3]   Gas separation membranes from polymers of intrinsic microporosity [J].
Budd, PM ;
Msayib, KJ ;
Tattershall, CE ;
Ghanem, BS ;
Reynolds, KJ ;
McKeown, NB ;
Fritsch, D .
JOURNAL OF MEMBRANE SCIENCE, 2005, 251 (1-2) :263-269
[4]   Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials [J].
Budd, PM ;
Ghanem, BS ;
Makhseed, S ;
McKeown, NB ;
Msayib, KJ ;
Tattershall, CE .
CHEMICAL COMMUNICATIONS, 2004, (02) :230-231
[5]   Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity [J].
Budd, PM ;
Elabas, ES ;
Ghanem, BS ;
Makhseed, S ;
McKeown, NB ;
Msayib, KJ ;
Tattershall, CE ;
Wang, D .
ADVANCED MATERIALS, 2004, 16 (05) :456-+
[6]   A nanoporous network polymer derived from hexaazatrinaphthylene with potential as an adsorbent and catalyst support [J].
Budd, PM ;
Ghanem, B ;
Msayib, K ;
McKeown, NB ;
Tattershall, C .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (11) :2721-2726
[7]   High H2 adsorption in a microporous metal-organic framework with open metal sites [J].
Chen, BL ;
Ockwig, NW ;
Millward, AR ;
Contreras, DS ;
Yaghi, OM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4745-4749
[8]   Synthesis of a novel poly(iptycene) ladder polymer [J].
Chen, ZH ;
Amara, JP ;
Thomas, SW ;
Swager, TM .
MACROMOLECULES, 2006, 39 (09) :3202-3209
[9]   Porous, crystalline, covalent organic frameworks [J].
Côté, AP ;
Benin, AI ;
Ockwig, NW ;
O'Keeffe, M ;
Matzger, AJ ;
Yaghi, OM .
SCIENCE, 2005, 310 (5751) :1166-1170
[10]   High surface area nanoporous polymers for reversible hydrogen storage [J].
Germain, Jonathan ;
Hradil, Jiri ;
Frechet, Jean M. J. ;
Svec, Frantisek .
CHEMISTRY OF MATERIALS, 2006, 18 (18) :4430-4435