Optical and electrical characterizations of cerium oxide thin films

被引:97
作者
Chiu, Fu-Chien [1 ]
Lai, Chih-Ming [1 ]
机构
[1] Ming Chuan Univ, Dept Elect Engn, Taoyuan Cty 333, Taiwan
关键词
DIELECTRIC-PROPERTIES; CEO2;
D O I
10.1088/0022-3727/43/7/075104
中图分类号
O59 [应用物理学];
学科分类号
摘要
The optical dielectric function of cerium oxide (CeO2) was characterized by the spectroscopic ellipsometry ( SE) technique using the Kramers-Kronig relation and the Tauc-Lorentz (TL) dispersion model. Experimental results showed that the bandgap energy and refractive index at 632.8 nm of CeO2 are about 3.23 +/- 0.05 eV and 2.33 +/- 0.08, respectively. Based on the optical properties, the electrical conduction mechanisms in CeO2 thin films are determined to be Schottky emission in a medium electric field (0.5-1.6 MV cm(-1)) from 350 to 500 K and Poole-Frenkel emission in a high electric field (>2.36 MV cm(-1)) from 450 to 500 K. Accordingly, the conduction band offsets between Al and CeO2 and the trap energy level are about 0.62 +/- 0.01 eV and 1.53 +/- 0.01 eV, respectively.
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页数:5
相关论文
共 30 条
[1]   Interfacial and Electrical Characterization in Metal-Oxide-Semiconductor Field-Effect Transistors with CeO2 Gate Dielectric [J].
Chiu, Fu-Chien ;
Chen, Shuang-Yuan ;
Chen, Chun-Heng ;
Chen, Hung-Wen ;
Huang, Heng-Sheng ;
Hwang, Huey-Liang .
JAPANESE JOURNAL OF APPLIED PHYSICS, 2009, 48 (04)
[2]   Interface engineering for Ge metal-oxide-semiconductor devices [J].
Dimoulas, A. ;
Brunco, D. P. ;
Ferrari, S. ;
Seo, J. W. ;
Panayiotatos, Y. ;
Sotiropoulos, A. ;
Conard, T. ;
Caymax, M. ;
Spiga, S. ;
Fanciulli, M. ;
Dieker, Ch. ;
Evangelou, E. K. ;
Galata, S. ;
Houssa, M. ;
Heyns, M. M. .
THIN SOLID FILMS, 2007, 515 (16) :6337-6343
[3]   Electron localization determines defect formation on ceria substrates [J].
Esch, F ;
Fabris, S ;
Zhou, L ;
Montini, T ;
Africh, C ;
Fornasiero, P ;
Comelli, G ;
Rosei, R .
SCIENCE, 2005, 309 (5735) :752-755
[4]   Correlation of Charge Buildup and Stress-Induced Leakage Current in Cerium Oxide Films Grown on Ge (100) Substrates [J].
Evangelou, Evangelos K. ;
Rahman, Shahinur ;
Dimoulas, A. .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2009, 56 (03) :399-407
[5]   Conductivity and dielectric properties of thin amorphous cerium dioxide films [J].
Grosse, V. ;
Bechstein, R. ;
Schmidl, F. ;
Seidel, P. .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2007, 40 (04) :1146-1149
[6]   SPECTROSCOPIC ELLIPSOMETRY STUDY OF CERIUM DIOXIDE THIN-FILMS GROWN ON SAPPHIRE BY RF MAGNETRON SPUTTERING [J].
GUO, S ;
ARWIN, H ;
JACOBSEN, SN ;
JARRENDAHL, K ;
HELMERSSON, U .
JOURNAL OF APPLIED PHYSICS, 1995, 77 (10) :5369-5376
[7]  
Gusev E.P., 2001, IEDM Tech. Dig, P451, DOI DOI 10.1109/IEDM.2001.979537
[8]   Thermodynamic stability of binary oxides in contact with silicon [J].
Hubbard, KJ ;
Schlom, DG .
JOURNAL OF MATERIALS RESEARCH, 1996, 11 (11) :2757-2776
[9]   EPITAXIAL-GROWTH OF CEO2 LAYERS ON SILICON [J].
INOUE, T ;
YAMAMOTO, Y ;
KOYAMA, S ;
SUZUKI, S ;
UEDA, Y .
APPLIED PHYSICS LETTERS, 1990, 56 (14) :1332-1333
[10]   DATA-ANALYSIS FOR SPECTROSCOPIC ELLIPSOMETRY [J].
JELLISON, GE .
THIN SOLID FILMS, 1993, 234 (1-2) :416-422