Polyazidopyrimidines: High-energy compounds and precursors to carbon nanotubes

被引：108
作者：
Ye, Chengfeng
Gao, Haixiang
Boatz, Jerry A.
Drake, Gregory W.
Twamley, Brendan
Shreeve, Jean'ne M. [1 ]
机构：
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
[2] USAF, Res Lab, Space & Missile Prop Div, Edwards AFB, CA 93524 USA
[3] NASA, Solid Propellants Branch ER22, Marshall Space Flight Ctr, Huntsville, AL 35812 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 43期
关键词：
azides; explosives; heats of formation; nanotubes; nitrogen;
D O I：
10.1002/anie.200602778
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) An additional azidomethyl group dramatically decreases the melting points of the corresponding azidopyrimidines. Theoretical calculations show that these polyazido compounds (see picture; N light blue, C dark blue, H white) exhibit highly promising energetic properties. 2,4,6-Triazidopyrimidine was found to be a novel precursor to carbon nanotubes in the presence of Ni(ClO4)2. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：7262 / 7265
页数：4
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