Reaction of [Pt(NH3)4]Cl2•H2O with (NH4)6Mo7O24•4H2O in an aqueous alkaline solution at 190A°C (autoclaving conditions)

被引：5

作者：

Fesik, E. V. ^{[1
,2
]}

Buslayeva, T. M. ^{[3
]}

Mel'nikova, T. I. ^{[4
]}

机构：

[1] Samara Univ, Moskovskoe Sh 34, Samara 443086, Russia

[2] Med Univ Reaviz, Samara, Russia

[3] Moscow State Technol Univ, Inst Fine Chem Technol, Moscow, Russia

[4] Nonprofit Partnership Assistance Chem & Environm, Moscow, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2017年 / 87卷 / 02期

关键词：

platinum; molybdenum; autoclaving conditions; thermolysis; FUEL-CELLS; NH4REO4;

D O I：

10.1134/S1070363217020013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A solid product formed during thermolysis of tetraammineplatinum(II) chloride and ammonium heptamolybdate in an aqueous alkaline solution under autoclaving conditions has been studied by means of dynamic light scattering, scanning electron microscopy, X-ray diffraction analysis, and elemental analysis. The amount of free ammonia formed in the reaction has been determined by titration. The pathway of platinum(II) and heptamolybdate ions reduction by inner-sphere ammonium into the corresponding metals has been proposed.

引用

页码：159 / 162

页数：4

共 50 条

[41] The Platinum(II) Salt Pt(H2O)4(SbF6)2 [J].

Seppelt, Konrad .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (13-14) :2391-2393

[42] X-ray Crystallographic Studies of a Bimetallic cis-Mo(CO)4(PPh2NH2CH2CH2N=CHC6H4-o-O)2Cu Complex, the Starting Material, cis-Mo(CO)4(PPh2Cl)2, and the Reaction Intermediates cis-Mo(CO)4(PPh2NH2CH2CH2NH2)2 and cis-Mo(CO)4(PPh2NH2CH2CH2N=CHC6H4-o-OH)2 [J].

Christina Duffey ;

Seth Stepleton ;

Mary Elizabeth Anderson ;

Daniel Cox ;

Marty Ready ;

Houston Byrd ;

Carrie A. Bloomfield ;

Jason L. Freeman ;

Gary M. Gray .

Journal of Chemical Crystallography, 2011, 41 :1560-1567

[43] X-ray Crystallographic Studies of a Bimetallic cis-Mo(CO)4(PPh2NH2CH2CH2N=CHC6H4-o-O)2Cu Complex, the Starting Material, cis-Mo(CO)4(PPh2Cl)2, and the Reaction Intermediates cis-Mo(CO)4(PPh2NH2CH2CH2NH2)2 and cis-Mo(CO)4(PPh2NH2CH2CH2N=CHC6H4-o-OH)2 [J].

Duffey, Christina ;

Stepleton, Seth ;

Anderson, Mary Elizabeth ;

Cox, Daniel ;

Ready, Marty ;

Byrd, Houston ;

Bloomfield, Carrie A. ;

Freeman, Jason L. ;

Gray, Gary M. .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (10) :1560-1567

[44] Synthesis and structural characterization of Mo2(μ-SC6H4-Cl-p)2(μ-dppm)(CO)6 and [(dppm)(CO)2Mo(μ-SC6H4-Cl-p)2Mo(O)]2(μ-SC6H4-Cl-p)2(μ-O) and electrochemical property of Mo2(μ-SC6H4-Cl-p)2(μ-dppm)(CO)6 [J].

Pan, GH ;

Zhuang, BT ;

He, LJ ;

Chen, JT ;

Lu, JX .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 580 (02) :313-319

[45] Synthesis and spectral characterization of a new molybdenum phosphate compound (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)]•7H2O [J].

Li, ZZ ;

Zhang, HH ;

Huang, CC ;

Sun, RQ ;

Zheng, XL .

SPECTROSCOPY AND SPECTRAL ANALYSIS, 2002, 22 (06) :1048-1050

[46] Crystal Structure and Thermal Properties of Double-Complex Salts [M1(NH3)6][M2(C2O4)3] (M1, M2 = Co, Rh) and K3[Rh(NH3)6][Rh(C2O4)3]2•6H2O [J].

Smirnov, Pavel ;

Filatov, Evgeny ;

Kuratieva, Natalia ;

Plyusnin, Pavel ;

Korenev, Sergey .

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2023, 24 (15)

[47] Synthesis and structural characterization of a new dinuclear platinum(III) complex, [Pt2Cl4(NH3)2-{μ-HN=C(O)But}2] [J].

Vinci, Doriana ;

Chateigner, Daniel .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2022, 78 (Pt 6) :835-841

[48] Selective synthesis of triangular cluster oxido-sulfidocomplexes of Mo and W: High yield preparations of [Mo3O2S2(H2O)9]4+, [W3O2S2(H2O)9]4+, [W2MoO2S2(H2O)9]4+ and their derivatization [J].

Abramov, Pavel A. ;

Sokolov, Maxim N. ;

Hernandez-Molina, Rita ;

Vicent, Cristian ;

Virovets, Alexander V. ;

Naumov, Dmitry Y. ;

Gili, Pedro ;

Gonzalez-Platas, Javier ;

Fedin, Vladimir P. .

INORGANICA CHIMICA ACTA, 2010, 363 (13) :3330-3337

[49] Synthesis and characterization of two new photochromic organic-inorganic hybrid materials based on isopolyoxomolybdate:: (HDBU)3(NH4)[β-Mo8O26] • H2O and (HDBU)4[δ-Mo8O26] [J].

Coue, Violaine ;

Dessapt, Remi ;

Bujoli-Doeuff, Martine ;

Evain, Michel ;

Jobic, Stephane .

JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (12) :3615-3627

[50] Crystal structure of new complexes of arsenitotungstates with triangular sulfido bridged clusters: Cs5.6K4.4[{Mo3S4(H2O)5}(H2AsW9O33)2]·19.15H2O and K6.35(NH4)2.65[{W3S4(H2O)5}(H2AsW9O33)(HAsW9O33AsOH)]·23.7H2O [J].

I. V. Kalinina ;

M. N. Sokolov ;

E. V. Chubarova ;

E. V. Peresypkina ;

V. P. Fedin .

Journal of Structural Chemistry, 2010, 51 :303-307

← 1 2 3 4 5 →