Reaction of [Pt(NH3)4]Cl2•H2O with (NH4)6Mo7O24•4H2O in an aqueous alkaline solution at 190A°C (autoclaving conditions)

被引：5

作者：

Fesik, E. V. ^{[1
,2
]}

Buslayeva, T. M. ^{[3
]}

Mel'nikova, T. I. ^{[4
]}

机构：

[1] Samara Univ, Moskovskoe Sh 34, Samara 443086, Russia

[2] Med Univ Reaviz, Samara, Russia

[3] Moscow State Technol Univ, Inst Fine Chem Technol, Moscow, Russia

[4] Nonprofit Partnership Assistance Chem & Environm, Moscow, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2017年 / 87卷 / 02期

关键词：

platinum; molybdenum; autoclaving conditions; thermolysis; FUEL-CELLS; NH4REO4;

D O I：

10.1134/S1070363217020013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A solid product formed during thermolysis of tetraammineplatinum(II) chloride and ammonium heptamolybdate in an aqueous alkaline solution under autoclaving conditions has been studied by means of dynamic light scattering, scanning electron microscopy, X-ray diffraction analysis, and elemental analysis. The amount of free ammonia formed in the reaction has been determined by titration. The pathway of platinum(II) and heptamolybdate ions reduction by inner-sphere ammonium into the corresponding metals has been proposed.

引用

页码：159 / 162

页数：4

共 50 条

[21] Synthesis and Structure of the Supramolecular Adduct Formed by the [Mo3S4(H2O)7Cl22+ Cluster Complex with Cucurbituril: {[Mo3S4(H2O)7Cl2](C36H36N24O12)} Cl2·10H2O [J].

E. V. Chubarova ;

D. G. Samsonenko ;

J. H. Platas ;

M. N. Sokolov ;

V. P. Fedin .

Journal of Structural Chemistry, 2004, 45 :906-911

[22] Structure and thermal properties of double complex salts [RuNO(NH 3)4(H2O)]2[MCl4]Cl 4·2H2O, M = Pt, Pd [J].

Plyusnina O.A. ;

Emel'yanov V.A. ;

Baidina I.A. ;

Plyusnin P.E. ;

Gromilov S.A. .

Journal of Structural Chemistry, 2011, 52 (1) :140-150

[23] [Ru(NH3)6](MoO4)Cl·3H2O and [M(NH3)6](ReO4)3·2H2O (M = Ru, Ir). Synthesis and crystal structure [J].

S. P. Khranenko ;

E. A. Bykova ;

K. V. Yusenko ;

A. P. Tyutyunnik ;

S. A. Gromilov .

Journal of Structural Chemistry, 2013, 54 :931-936

[24] Synthesis and structural characterization of a single crystal of [Na2(H2O)10](NH4)3(NH3)[MoV9O28] [J].

Wang, Shou-Jiang ;

Dong, Wen-Kui ;

Chen, Yan-Mei .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2006, 36 (09) :649-653

[25] Crystal structure and thermal properties of [Pt(NH3)5Cl][ReCl6]Cl·H2O [J].

A. V. Zadesenets ;

I. V. Korol’kov ;

S. A. Gromilov .

Journal of Structural Chemistry, 2013, 54 :201-205

[26] Crystal structure and thermal properties of [Pt(NH3)5Cl][ReCl6]Cl•H2O [J].

Zadesenets, A. V. ;

Korol'kov, I. V. ;

Gromilov, S. A. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 54 (01) :201-205

[27] Selective Oxidation of Sulfides Catalyzed by the Nanocluster Polyoxomolybdate (NH4)12[Mo36(NO)4O108(H2O)16] [J].

Amini, Mojtaba ;

Naslhajian, Hadi ;

Farnia, S. Morteza F. ;

Holynska, Malgorzata .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (23) :3873-3878

[28] Bimetallic single-source precursors [M(NH3)4][Co(C2O4)2(H2O)2]•2H2O (M = Pd, Pt) for the one run synthesis of CoPd and CoPt magnetic nanoalloys [J].

Zadesenets, Andrey ;

Filatov, Evgeny ;

Plyusnin, Pavel ;

Baidina, Iraida ;

Dalezky, Vasiliy ;

Shubin, Yuri ;

Korenev, Sergey ;

Bogomyakov, Artyom .

POLYHEDRON, 2011, 30 (07) :1305-1312

[29] Synthesis and structure of the first dinuclear lanthanide oxalato complexes [{MO2vO4(C2O4)2(H2O)2}2{(Ln2(H2O)4)2(C2O4)}]•7H2O (Ln = La3+, Ce3+) [J].

Mialane, P ;

Dolbecq, A ;

Costaz, G ;

Lisnard, L ;

Marrot, J ;

Sécheresse, F .

INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (09) :702-705

[30] Thermolysis of [Co(NH3)6][Cr(C2O4)3] [J].

S. I. Pechenyuk ;

D. P. Domonov ;

A. T. Belyaevskii .

Russian Journal of Inorganic Chemistry, 2008, 53 :1221-1226

← 1 2 3 4 5 →