Reaction of [Pt(NH3)4]Cl2•H2O with (NH4)6Mo7O24•4H2O in an aqueous alkaline solution at 190A°C (autoclaving conditions)

被引：5
|
作者：
Fesik, E. V. [1 ,2 ]
Buslayeva, T. M. [3 ]
Mel'nikova, T. I. [4 ]
机构：
[1] Samara Univ, Moskovskoe Sh 34, Samara 443086, Russia
[2] Med Univ Reaviz, Samara, Russia
[3] Moscow State Technol Univ, Inst Fine Chem Technol, Moscow, Russia
[4] Nonprofit Partnership Assistance Chem & Environm, Moscow, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2017年 / 87卷 / 02期
关键词：
platinum; molybdenum; autoclaving conditions; thermolysis; FUEL-CELLS; NH4REO4;
D O I：
10.1134/S1070363217020013
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A solid product formed during thermolysis of tetraammineplatinum(II) chloride and ammonium heptamolybdate in an aqueous alkaline solution under autoclaving conditions has been studied by means of dynamic light scattering, scanning electron microscopy, X-ray diffraction analysis, and elemental analysis. The amount of free ammonia formed in the reaction has been determined by titration. The pathway of platinum(II) and heptamolybdate ions reduction by inner-sphere ammonium into the corresponding metals has been proposed.
引用
收藏
页码：159 / 162
页数：4
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