2,4-Dibromo-6-{(E)-[(R)-1-phenylethyl]iminomethyl}phenol

被引：6

作者：

Xia, Dong-Guo ^{[1
]}

Ye, Ya-Fen ^{[1
]}

Lei, Ke-Wei ^{[1
]}

机构：

[1] Ningbo Univ, Fac Mat Sci & Chem Engn, Inst Solid Mat Chem, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

D O I：

10.1107/S1600536809044638

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title Schiff base, C(15)H(13)Br(2)NO, the benzene and phenyl rings form a dihedral angle of 75.18 (13)degrees. The N=C bond length of 1.263 (6) angstrom is shorter than of the N-C bond [1.476 (5) angstrom], indicating a double bond. In the crystal, there is some pseudosymmetry. This occurs because most of the two molecules are centrosymmetrically related. The molecular structure is stabilized by intramolecular O-H center dot center dot center dot N hydrogen bonds.

引用

页码：O3168 / U1258

页数：10

共 5 条

[1] Bruker, 2007, APEX2 SAINT
[2] TOPOCHEMISTRY .6. EXPERIMENTS ON PHOTOCHROMY + THERMOCHROMY OF CRYSTALLINE ANILS OF SALICYLALDEHYDES
COHEN, MD
SCHMIDT, GMJ
FLAVIAN, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JUN): : 2041 - &
[3] ON ENANTIOMORPH-POLARITY ESTIMATION
FLACK, HD
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV): : 876 - 881
[4] Sheldrick G.M., 2000, SADABS
[5] A short history of SHELX
Sheldrick, George M.
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122

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