A temperature-reduced method for the rapid growth of hybrid perovskite single crystals with primary alcohols

被引:12
作者
Hoecker, Julian [1 ,2 ]
Brust, Felix [1 ,2 ]
Armer, Melina [1 ,2 ]
Dyakonov, Vladimir [1 ,2 ,3 ]
机构
[1] Julius Maximilian Univ Wurzburg, Expt Phys 6, D-97074 Wurzburg, Germany
[2] Julius Maximilian Univ Wurzburg, Wurzburg Dresden Cluster Excellence Ct Qmat, D-97074 Wurzburg, Germany
[3] Bavarian Ctr Appl Energy Res ZAE Bayern, Magdalene Schoch Str 3, D-97074 Wurzburg, Germany
关键词
Compendex;
D O I
10.1039/d0ce01759k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The blends of primary alcohols and organo-lead trihalide perovskite (OLTP) precursor solutions with the stoichiometry ABX(3) (A = MA(+) or FA(+); B = Pb2+; X = Cl-, Br- or I-) lead to a significant reduction in their retrograde solubilities, which enables a temperature-reduced crystallisation pathway to grow high-quality single crystals.
引用
收藏
页码:2202 / 2207
页数:6
相关论文
共 38 条
[1]   Low-Temperature Crystallization Enables 21.9% Efficient Single-Crystal MAPbI3 Inverted Perovskite Solar Cells [J].
Alsalloum, Abdullah Y. ;
Turedi, Bekir ;
Zheng, Xiaopeng ;
Mitra, Somak ;
Zhumekenov, Ayan A. ;
Lee, Kwang Jae ;
Maity, Partha ;
Gereige, Issam ;
AlSaggaf, Ahmed ;
Rogan, Iman S. ;
Mohammed, Omar F. ;
Bakr, Osman M. .
ACS ENERGY LETTERS, 2020, 5 (02) :657-+
[2]   Single Crystal Perovskite Solar Cells: Development and Perspectives [J].
Cheng, Xiao ;
Yang, Shuang ;
Cao, Bingqiang ;
Tao, Xutang ;
Chen, Zhaolai .
ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (04)
[3]   Crystal orientation-dependent optoelectronic properties of MAPbCl3 single crystals [J].
Cheng, Xiaohua ;
Jing, Lin ;
Zhao, Ying ;
Du, Songjie ;
Ding, Jianxu ;
Zhou, Tianliang .
JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (06) :1579-1586
[4]   Bulk crystal growth of hybrid perovskite material CH3NH3PbI3 [J].
Dang, Yangyang ;
Liu, Yang ;
Sun, Youxuan ;
Yuan, Dongsheng ;
Liu, Xiaolong ;
Lu, Weiqun ;
Liu, Guangfeng ;
Xia, Haibing ;
Tao, Xutang .
CRYSTENGCOMM, 2015, 17 (03) :665-670
[5]   Electron-hole diffusion lengths > 175 μm in solution-grown CH3NH3PbI3 single crystals [J].
Dong, Qingfeng ;
Fang, Yanjun ;
Shao, Yuchuan ;
Mulligan, Padhraic ;
Qiu, Jie ;
Cao, Lei ;
Huang, Jinsong .
SCIENCE, 2015, 347 (6225) :967-970
[6]   RELATIONSHIP BETWEEN REDUCED CELLS IN A GENERAL BRAVAIS LATTICE [J].
GRUBER, B .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1973, A 29 (JUL1) :433-440
[7]   Room temperature synthesis of perovskite (MAPbI3) single crystal by antisolvent assisted inverse temperature crystallization method [J].
Gupta, Ramashanker ;
Korukonda, Tulja Bhavani ;
Gupta, Shailendra Kumar ;
Dhamaniya, Bhanu Pratap ;
Chhillar, Priyanka ;
Datt, Ram ;
Vashishtha, Pargam ;
Gupta, Govind ;
Gupta, Vinay ;
Srivastava, Ritu ;
Pathak, Sandeep .
JOURNAL OF CRYSTAL GROWTH, 2020, 537
[8]   MOLECULAR CONNECTIVITY .2. RELATIONSHIP TO WATER SOLUBILITY AND BOILING-POINT [J].
HALL, LH ;
KIER, LB ;
MURRAY, WJ .
JOURNAL OF PHARMACEUTICAL SCIENCES, 1975, 64 (12) :1974-1977
[9]   Single Crystal Formamidinium Lead Iodide (FAPbI3): Insight into the Structural, Optical, and Electrical Properties [J].
Han, Qifeng ;
Bae, Sang-Hoon ;
Sun, Pengyu ;
Hsieh, Yao-Tsung ;
Yang, Yang ;
Rim, You Seung ;
Zhao, Hongxiang ;
Chen, Qi ;
Shi, Wangzhou ;
Li, Gang ;
Yang, Yang .
ADVANCED MATERIALS, 2016, 28 (11) :2253-2258
[10]   Seed crystal free growth of high-quality double cation - double halide perovskite single crystals for optoelectronic applications [J].
Hoecker, Julian ;
Ozcan, Mehmet ;
Hammer, Sebastian ;
Fischer, Mathias ;
Bichler, Benedikt ;
Armer, Melina ;
Rieder, Philipp ;
Drach, Volker ;
Pflaum, Jens ;
Nickel, Bert ;
Dyakonov, Vladimir .
JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8 (24) :8275-8283