Hydrothermal synthesis, structure and properties of a novel Zn(II) dicarboxylate containing nanometer channel by significant hydrogen bonds and π-π interactions

被引：2

作者：

Zhu, Yong-Min

Wang, Peng

Zhou, Hong-Ping

Yang, Jia-Xiang

Wu, Jie-Ying

Yang, Lin

Tian, Yu-Peng ^{[1
]}

Jiang, Min-Hua

Tao, Xu-Tang

机构：

[1] Anhui Univ, Dept Chem, Hefei 230039, Peoples R China

[2] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2007年 / 32卷 / 01期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1007/s11243-006-0140-z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A two-dimensional supramolecular complex, [Zn(HA)(2)(hmta)] center dot 2H(2)O (1) (H(2)A: 9-ethylcarbazole-3,6-dicarboxylic acid, hmta: 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane), has been prepared by hydrothermal synthesis and characterized by IR spectra, elemental analysis, TG analysis. The result of single crystal X-ray analysis revealed that the 2D supramolecular open framework contains 9.932 x 12.059 angstrom channels formed by significant hydrogen bonds and pi-pi interactions. Furthermore, the solid state fluorescent determinations show that the complex exhibits a strong emission band at 432 nm.

引用

页码：136 / 139

页数：4

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