First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF:: Co2M(PhCOO)6(TTF-CH=CHpy)2•2CH3CN, M = CoII, MnII

被引：65

作者：

Gavrilenko, Konstantin S. ^{[1
]}

Le Gal, Yann ^{[1
]}

Cador, Olivier ^{[1
]}

Golhen, Stephane ^{[1
]}

Ouahab, Lahcene ^{[1
]}

机构：

[1] Univ Rennes 1, UMR 6226, CNRS, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 03期

关键词：

D O I：

10.1039/b613191c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first paramagnetic homo- and hetero-metallic trinuclear complexes with redox active ligands derived from TTF are synthesized, the central metal ion has an octahedral coordination sphere while the outer Co-II ions are in a distorted bipyramidal surrounding, bearing TTF-ligands, the magnetic properties show antiferromagnetic coupling leading to a magnetic ground state.

引用

页码：280 / 282

页数：3

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