Synthesis and Stille Cross-Coupling Reactions of 2-(Tributylstannyl)- and 2,5-Bis(trimethylstannyl)tellurophene

被引：22
|
作者：
Sweat, Daniel P. [1 ]
Stephens, Chad E. [1 ]
机构：
[1] Augusta State Univ, Dept Chem & Phys, Augusta, GA 30904 USA
来源：
SYNTHESIS-STUTTGART | 2009年 / 19期
关键词：
tellurophene; Stille reaction; cross-coupling; palladium; heterocyclic; IN-VITRO; TELLUROPHENE; DERIVATIVES; FLUORIDE; AGENTS;
D O I：
10.1055/s-0029-1216958
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Herein, we describe the synthesis and Stille cross-coupling reactions of 2-(tributylstannyl)- and 2,5-bis(trimethylstannyl)tellurophene. The reactions were most optimal when using aryl iodides as coupling partners, and a mixed catalyst system consisting of tetrakis(triphenylphosphine)palladium(0) and copper(I) iodide, together with cesium fluoride as additive, in N,N-dimethylformamide. This is the first reported synthesis and use of stannylated tellurophenes for cross-coupling reactions.
引用
收藏
页码：3214 / 3218
页数：5
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