Recent advances in the syntheses and applications of molybdenum and tungsten alkylidene and alkylidyne catalysts for the metathesis of alkenes and alkynes

被引：225

作者：

Schrock, Richard R. ^{[1
]}

Czekelius, Constantin ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 1-2期

关键词：

alkenes; alkynes; metathesis; molybdenum; tungsten;

D O I：

10.1002/adsc.200600459

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The last several years have produced some key advances in the area of alkene and alkyne metathesis by high oxidation state alkylidene and alkylidyne complexes along with new applications in organic and polymer chemistry. In this review we cover some of these developments and applications. The first part of this review concerns developments in catalyst synthesis and new catalysts. The second part concerns notable applications in organic and polymer chemistry. We discuss only high oxidation state alkylidene and alkylidyne chemistry of relevance to alkene or alkyne metathesis reactions and favor studies in the homogeneous phase.

引用

页码：55 / 77

页数：23

共 167 条

[1] Initiators of the type Mo(NAr)(CHR′)(OR")2 for the controlled polymerization of diethyldipropargylmalonate [J].