Study of passivation at the positive active material/grid interface in lead-acid batteries

A valuable additive - boric acid - to eliminate passivation of the active material/grid interface in positive plates of lead-acid batteries has been selected through comparison of single-cell discharge tests. This overcomes the problem of rapid decline in initial performance when using low-antimony (1.7 wt.%) grid alloys. The performance of the oxide film on positive grids, as well as its composition and amount, is determined through cathodic reduction of the film with a linear sweep voltammetric (LSV) method. The results confirm that passivation of the positive grid and rapid decline in the initial discharge voltage are due to a resistive layer of PbSO4, and not PbOn, (1 less than or equal to n less than or equal to 2). The PbOn layer has little effect on passivation. The findings of this study are useful for the production of lead-acid batteries. (C) 2000 Elsevier Science S.A. All rights reserved.