Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses

被引：78

作者：

Petit, L. ^{[1
]}

Carlie, N. ^{[1
]}

Chen, H. ^{[1
]}

Gaylord, S. ^{[1
]}

Massera, J. ^{[1
]}

Boudebs, G. ^{[2
]}

Hu, J. ^{[3
]}

Agarwal, A. ^{[3
]}

Kimerling, L. ^{[3
]}

Richardson, K. ^{[1
]}

机构：

[1] Clemson Univ, Sch Mat Sci & Engn, Clemson, SC 29634 USA

[2] Univ Angers, CNRS, UMR 6163, Lab Proprietes Opt Mat & Applicat, F-49045 Angers 01, France

[3] MIT, Microphoton Ctr, Cambridge, MA 02139 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2009年 / 182卷 / 10期

基金：

美国国家科学基金会;

关键词：

Chalcogenide glass; Nonlinear refractive index; Raman spectroscopy; OPTICAL-PROPERTIES; CHALCOHALIDE GLASSES; RAMAN GAIN; STRUCTURAL-PROPERTIES; 2-PHOTON ABSORPTION; SULFIDE GLASSES; SYSTEM; 3RD-ORDER; TELLURITE; FIBER;

D O I：

10.1016/j.jssc.2009.07.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

in this paper, we report results Of n(2) measurements of new chalcogenide glasses in the Ge-Sb-S-Se system using a modified Z-Scan technique. Measurements were made with picosecond pulses emitted by a 10 Hz Q-switched mode-locked Nd-YAG laser at 1064 nm under conditions suitable to characterize ultrafast nonlinearities. The nonlinear index increases up to 500 times the n2 of fused silica with an increase in the Ge/Se ratio and a decrease with an increase of the Ge/Sb ratio. We confirmed, using Raman spectroscopy, that the nonlinear refractive index depends oil the number of Ge-S(Se) and Sb-S(Se) bonds in the glass network. Sulfide glasses were shown to have a nonlinear FOM near or <1, at 1064 nm. (C) 2009 Elsevier Inc. All rights reserved.

引用

页码：2756 / 2761

页数：6

共 36 条

[1] CAO Y, 2008, ACTA PHOTON SIN, V37, P203
[2] Non-linear optical properties of chalcogenide glasses in the system As-S-Se
Cardinal, T
Richardson, KA
Shim, H
Schulte, A
Beatty, R
Le Foulgoc, K
Meneghini, C
Viens, JF
Villeneuve, A
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1999, 256 : 353 - 360
[3] SbS3 enhanced ultrafast third-order optical nonlinearities of Ge-S chalcogenide glasses at 820 nm
Chu, Saisai
Li, Fengming
Tao, Haizheng
Yang, Hong
Wang, Shufeng
Lin, Changgui
Zhao, Xiujian
Gong, Qihuang
[J]. OPTICAL MATERIALS, 2008, 31 (02) : 193 - 195
[4] Synthesis and optical properties of the Ge-Sb-S:PrCl3 glass system
Frumarová, B
Nemec, P
Frumar, M
Oswald, J
Vlcek, M
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1999, 256 : 266 - 270
[5] Nonlinear optical properties of antimony-germanium-sulfur glasses at 1560 nm
Gomez, L. A.
de Araujo, C. B.
Putvinskis, R., Jr.
Messaddeq, S. H.
Ledemi, Y.
Messaddeq, Y.
[J]. APPLIED PHYSICS B-LASERS AND OPTICS, 2009, 94 (03): : 499 - 502
[6] Optical and structural properties of new chalcohalide glasses
Guignard, M.
Nazabal, V.
Moreac, A.
Cherukulappurath, S.
Boudebs, G.
Zeghlache, H.
Martinelli, G.
Quiquempois, Y.
Smektala, F.
Adam, J. -L.
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2008, 354 (12-13) : 1322 - 1326
[7] Third- and second-order optical nonlinearity of Ge-Ga-S-PbI2 chalcohalide glasses
Guo, Haitao
Tao, Haizheng
Gu, Shaoxuan
Zheng, Xiaolin
Zhai, Yanbo
Chu, Saisai
Zhao, Xiujian
Wang, Shufeng
Gong, Qihuang
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (01) : 240 - 248
[8] Highly nonlinear Ge-As-Se and Ge-As-S-Se glasses for all-optical switching
Harbold, JM
Ilday, FÖ
Wise, FW
Aitken, BG
[J]. IEEE PHOTONICS TECHNOLOGY LETTERS, 2002, 14 (06) : 822 - 824
[9] Selenide glass single mode optical fiber for nonlinear optics
Houizot, Patrick
Smektala, Frederic
Couderc, Vincent
Troles, Johann
Grossard, Ludovic
[J]. OPTICAL MATERIALS, 2007, 29 (06) : 651 - 656
[10] On the structural phase transformations in GexSb40-xSe60 glasses
Ivanova, ZG
Pamukchieva, V
Vlcek, M
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 293 : 580 - 585

← 1 2 3 4 →