Kinetic Resolution: A Powerful Tool for the Synthesis of Planar-Chiral Ferrocenes

被引：42

作者：

Alba, Andrea-Nekane R. ^{[1
]}

Rios, Ramon ^{[1
]}

机构：

[1] Univ Barcelona, Dept Organ Chem, E-08028 Barcelona, Spain

来源：

MOLECULES | 2009年 / 14卷 / 11期

关键词：

ferrocene; kinetic resolution; planar chirality; CATALYZED ENANTIOSELECTIVE METATHESIS; DIASTEREOSELECTIVE ORTHO-LITHIATION; LIPASE-MEDIATED RESOLUTION; ASYMMETRIC ALDOL REACTION; METAL-COMPLEXES; DERIVATIVES; ALDEHYDES; SULFOXIDES; LIGANDS;

D O I：

10.3390/molecules14114747

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Since the serendipitous discovery of ferrocene by Pauson and Kealy in 1951, it has become one of the most important structures in Organic Chemistry. Lately, kinetic resolution has emerged as a useful tool for the synthesis of planar chiral ferrocenes. This review aims to cover and discuss the development of this topic.

引用

页码：4747 / 4757

页数：11

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