Kinetic Resolution: A Powerful Tool for the Synthesis of Planar-Chiral Ferrocenes

被引：42

作者：

Alba, Andrea-Nekane R. ^{[1
]}

Rios, Ramon ^{[1
]}

机构：

[1] Univ Barcelona, Dept Organ Chem, E-08028 Barcelona, Spain

来源：

MOLECULES | 2009年 / 14卷 / 11期

关键词：

ferrocene; kinetic resolution; planar chirality; CATALYZED ENANTIOSELECTIVE METATHESIS; DIASTEREOSELECTIVE ORTHO-LITHIATION; LIPASE-MEDIATED RESOLUTION; ASYMMETRIC ALDOL REACTION; METAL-COMPLEXES; DERIVATIVES; ALDEHYDES; SULFOXIDES; LIGANDS;

D O I：

10.3390/molecules14114747

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Since the serendipitous discovery of ferrocene by Pauson and Kealy in 1951, it has become one of the most important structures in Organic Chemistry. Lately, kinetic resolution has emerged as a useful tool for the synthesis of planar chiral ferrocenes. This review aims to cover and discuss the development of this topic.

引用

页码：4747 / 4757

页数：11

共 32 条

[1] Organocatalytic kinetic resolution of a planar-chiral ferrocenecarbaldehyde
Alba, Andrea-Nekane
Gomez-Sal, Pilar
Rios, Ramon
Moyano, Albert
[J]. TETRAHEDRON-ASYMMETRY, 2009, 20 (11) : 1314 - 1318
[2] [Anonymous], TETRAHEDRON LETT
[3] Asymmetric dihydroxylation of 2-substituted 1-vinylferrocenes:: The first non-enzymatic kinetic resolution of planar-chiral ferrocenes
Bueno, Agusti
Rosol, Malgorzata
Garcia, Jason
Moyano, Albert
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (18) : 2590 - 2596
[4] CATALYTIC ASYMMETRIC HYDROSILYLATION OF 1,3-DIENES WITH NEW CHIRAL FERROCENYLPHOSPHINE-PALLADIUM COMPLEXES
HAYASHI, T
MATSUMOTO, Y
MORIKAWA, I
ITO, Y
[J]. TETRAHEDRON-ASYMMETRY, 1990, 1 (03) : 151 - 154
[5] ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE TRANSITION-METAL COMPLEXES .6. PRACTICAL ASYMMETRIC-SYNTHESIS OF 1,1'-BINAPHTHYLS VIA ASYMMETRIC CROSS-COUPLING WITH A CHIRAL [(ALKOXYALKYL)FERROCENYL]MONOPHOSPHINE NICKEL-CATALYST
HAYASHI, T
HAYASHIZAKI, K
KIYOI, T
ITO, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (24) : 8153 - 8156
[6] HAYASHI T, 1976, TETRAHEDRON LETT, V17, P1133
[7] CATALYTIC ASYMMETRIC ALDOL REACTION - REACTION OF ALDEHYDES WITH ISOCYANOACETATE CATALYZED BY A CHIRAL FERROCENYLPHOSPHINE-GOLD(I) COMPLEX
ITO, Y
SAWAMURA, M
HAYASHI, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (20) : 6405 - 6406
[8] ENZYMATIC KINETIC RESOLUTION OF [4](1,2)FERROCENOPHANE DERIVATIVES
IZUMI, T
TAMURA, F
SASAKI, K
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (10) : 2784 - 2788
[9] Keith JM, 2001, ADV SYNTH CATAL, V343, P5, DOI 10.1002/1615-4169(20010129)343:1<5::AID-ADSC5>3.3.CO
[10] 2-9

← 1 2 3 4 →